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- W3215397712 abstract "Controlled synthesis of metal–organic framework (MOF)-derived Mg-Zn hybrid nanostructure was demonstrated for the development of basic catalysts applied in biodiesel production from soybean oil. Two types of Mg-Zn hybrid nanostructures were successfully fabricated under different atmospheres (Ar, air), (1) MgO nanoparticles encapsulated in Zn-based MOF ([email protected]) and (2) MgO nanoparticles uniformly decorated on ZnO nanoparticles derived from Zn-MOF ([email protected]), respectively. Ultrafine MgO nanoparticles (<5 nm for [email protected] and ≈10 nm for [email protected]) were successfully synthesized and homogeneously dispersed in the MOF-derived Mg-Zn hybrid nanostructures. Significant increases in the specific surface area (i.e., a maximum of 1048.5 m2/g) and corresponding basicity (i.e., by a maximum of 2.1 times) were achievable by using MOF-based strategy comparing to the Mg-Zn catalyst prepared by a conventional solution-based approach. High 3-cycle stability and high yields of fatty acid methyl esters at a stoichiometric feed ratio 3 were both achievable, 67.6% and 73.3%, by using [email protected] and [email protected] as the catalysts, respectively. The work demonstrates a prototype study of utilizing MOF to develop high-performance basic nanocatalysts through fundamental understanding of material synthesis by design versus their corresponding activities." @default.
- W3215397712 created "2021-12-06" @default.
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- W3215397712 date "2022-01-01" @default.
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- W3215397712 title "Metal-organic framework-derived Mg-Zn hybrid nanocatalyst for biodiesel production" @default.
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- W3215397712 doi "https://doi.org/10.1016/j.apt.2021.11.017" @default.
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