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• W3215431304 abstract "The key to developing new infrared nonlinear optical (NLO) materials is balancing second-order nonlinear optical effects and the laser-induced damage threshold (LIDT). In this paper, a new polymorph of HgBr2 (P212121) was synthesized by a halogen-ion-induced effect in solution, which features a crystal structure different from that of the original phase (Cmc21) and exhibits better NLO properties. Its powders show a strong SHG effect (9 × KDP), a high LIDT (30 × AgGaS2), a wide infrared transparent range, and stability in air, making it a prospective NLO material in the IR region. In addition, the above excellent NLO characteristics are well illustrated in DFT theoretical calculations. More importantly, experimental results show that the new infrared NLO polymorph with excellent comprehensive properties could be controllably obtained by using the halogen-ion-induced strategy." @default.
• W3215431304 created "2021-12-06" @default.
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• W3215431304 date "2021-12-02" @default.
• W3215431304 modified "2023-10-14" @default.
• W3215431304 title "Halogen-Ion-Induced Structural Phase Transition Giving a Polymorph of HgBr₂ with Balanced Nonlinear Optical Properties" @default.
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• W3215431304 doi "https://doi.org/10.1021/acs.inorgchem.1c03099" @default.
• W3215431304 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34854664" @default.
• W3215431304 hasPublicationYear "2021" @default.
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