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• W3215572793 endingPage "13234" @default.
• W3215572793 startingPage "13229" @default.
• W3215572793 abstract "Coordination nanocages (CNCs) are under intense research in nanoscience and supramolecular chemistry for their enriched surface functionalities and micro-porosity; however, the understanding of their formation mechanism is still poor due to the difficulty in probing their solution structures. Herein, the CNC formation process from the coordination complexation of the macromolecular isophthalic acid (IPA) ligand and Cu2+ is studied via isothermal titration calorimetry, and its entropy-driven feature is revealed to be originated from the collapse of solvation layers of the assembly units. The CNC formation is thermodynamically less favored with smaller binding constants when the sizes of macromolecular IPA ligands are larger, which originated from the space crowding of macromolecules of the ligands on CNC surfaces and the resulting entropy loss of polymer chain conformations. Meanwhile, the chemical equilibrium of CNC formation can be tuned upon altering the Cu2+/IPA ratio, and the yield of CNCs, suggested from size exclusion chromatography studies, decreases when excessive Cu2+ is applied, providing guidelines for CNC design and synthesis." @default.
• W3215572793 created "2021-12-06" @default.
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• W3215572793 date "2021-11-22" @default.
• W3215572793 modified "2023-10-18" @default.
• W3215572793 title "Surface Functionality-Regulated and Entropy-Driven Thermodynamics of the Formation of Coordination Nanocages" @default.
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• W3215572793 doi "https://doi.org/10.1021/acs.jpcb.1c06690" @default.
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• W3215572793 hasPublicationYear "2021" @default.
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