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• W3215694036 endingPage "111572" @default.
• W3215694036 startingPage "111572" @default.
• W3215694036 abstract "Ethane-selective adsorbents for separating ethane (C2H6)/ethylene (C2H4) gas mixtures have attracted considerable interest as promising alternatives to conventional cryogenic distillation because of the possibility of directly producing high-purity C2H4 (>99.95%). Herein, CAU-3-NDCA built by the coordination bond between [Al12(OCH3)24]12+ and 2,6-naphthalenedicarboxylic acid (NDCA) was evaluated for use as a C2H6-selective adsorbent for separating a C2H6/C2H4 gas mixture. The separation performance of the adsorbents was investigated using single-component gas isotherms, ideal adsorbed solution theory calculations, dynamic breakthrough experiments for gas mixture, and molecular simulations, such as Monte Carlo simulation and density functional theory calculation. CAU-3-NDCA displayed exceptional adsorption capacity (9.2–10.2 mmol g−1 at 15 bar) and good C2H6/C2H4 selectivity (1.44–1.56) in the temperature range 293–313 K. In the breakthrough experiments, the C2H6/C2H4 separation performance of CAU-3-NDCA exhibited high-purity C2H4 productivity of 6.6 and 25.7 LSTP kg−1 under a 50/50 (v/v) and 10/90 (v/v) C2H6/C2H4 gas mixture, respectively, at 298 K and 7 bar. Recyclability was evaluated by a multi-cyclic breakthrough test for five cycles with a 10/90 (v/v) C2H6/C2H4 gas mixture. Molecular simulations indicated that the preferential adsorption of C2H6 originates from the higher affinity strength of multiple C–H···π interactions of C2H6 with NDCA linkers, in addition to the stronger methyl group–gas interaction of the methanolate group than those of C2H4. Moreover, it is characterised by thermal and moisture stability. Therefore, CAU-3-NDCA is a promising candidate for pressure swing adsorption operation as a C2H6-selective adsorbent." @default.
• W3215694036 created "2021-12-06" @default.
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• W3215694036 date "2022-01-01" @default.
• W3215694036 modified "2023-10-18" @default.
• W3215694036 title "Separation of ethane/ethylene gas mixture by ethane-selective CAU-3-NDCA adsorbent" @default.
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• W3215694036 cites W1981368803 @default.
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• W3215694036 cites W1989036019 @default.
• W3215694036 cites W1994839037 @default.
• W3215694036 cites W2001884976 @default.
• W3215694036 cites W2011397821 @default.
• W3215694036 cites W2019744287 @default.
• W3215694036 cites W2026505609 @default.
• W3215694036 cites W2027900786 @default.
• W3215694036 cites W2036113194 @default.
• W3215694036 cites W2037498697 @default.
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• W3215694036 cites W2046833966 @default.
• W3215694036 cites W2058246220 @default.
• W3215694036 cites W2065683180 @default.
• W3215694036 cites W2066681408 @default.
• W3215694036 cites W2087139813 @default.
• W3215694036 cites W2087585288 @default.
• W3215694036 cites W2099486431 @default.
• W3215694036 cites W2112061895 @default.
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• W3215694036 cites W2159752439 @default.
• W3215694036 cites W2163335877 @default.
• W3215694036 cites W2164664732 @default.
• W3215694036 cites W2173443714 @default.
• W3215694036 cites W2263926059 @default.
• W3215694036 cites W2317401029 @default.
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• W3215694036 cites W2324967581 @default.
• W3215694036 cites W2339540635 @default.
• W3215694036 cites W2345982147 @default.
• W3215694036 cites W2513299670 @default.
• W3215694036 cites W2570699173 @default.
• W3215694036 cites W2610258358 @default.
• W3215694036 cites W2734710423 @default.
• W3215694036 cites W2754628607 @default.
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• W3215694036 cites W2793204460 @default.
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• W3215694036 cites W2897403085 @default.
• W3215694036 cites W2897623214 @default.
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• W3215694036 doi "https://doi.org/10.1016/j.micromeso.2021.111572" @default.
• W3215694036 hasPublicationYear "2022" @default.
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