FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3215762237> ?p ?o ?g. }

• W3215762237 endingPage "18853" @default.
• W3215762237 startingPage "18843" @default.
• W3215762237 abstract "The development of Fischer-type electrophilic carbene chemistry with early transition metals has been a great challenge due to the fact that such metals in their high oxidation states lack the d electrons to stabilize the electrophilic carbene. Herein, we disclose the first experimental and theoretical findings of in situ transformation of an sp2 carbanion to a Fischer-type electrophilic carbene with rare-earth metals in their high oxidation state with a d0 electron via electron transfer. The carbene may undergo 1,1-migratory insertion into an adjacent RE-C(sp3) bond, and an unprecedented ring opening of the indole ring of the ligand occurs when the carbenes undergo nucleophilic substitution with a special organolithium reagent o-Me2NC6H4CH2Li. The key to success is the uniquely tailored novel ligand systems featuring a suitable conjugate building block (-C═C-C═N) bearing an sp2 carbanion connected to the rare-earth metal center." @default.
• W3215762237 created "2021-12-06" @default.
• W3215762237 creator A5003466470 @default.
• W3215762237 creator A5009188475 @default.
• W3215762237 creator A5010058446 @default.
• W3215762237 creator A5026853563 @default.
• W3215762237 creator A5031646142 @default.
• W3215762237 creator A5035477427 @default.
• W3215762237 creator A5038360481 @default.
• W3215762237 creator A5057012498 @default.
• W3215762237 creator A5086339701 @default.
• W3215762237 date "2021-11-30" @default.
• W3215762237 modified "2023-10-17" @default.
• W3215762237 title "Transformation of the sp² Carbanion to Carbene with Subsequent 1,1-Migratory Insertion and Nucleophilic Substitution in Rare-Earth Metal Chemistry" @default.
• W3215762237 cites W1964651302 @default.
• W3215762237 cites W1974464721 @default.
• W3215762237 cites W1981141489 @default.
• W3215762237 cites W1982567581 @default.
• W3215762237 cites W1991600639 @default.
• W3215762237 cites W1995484835 @default.
• W3215762237 cites W1997254481 @default.
• W3215762237 cites W1999364994 @default.
• W3215762237 cites W2000222777 @default.
• W3215762237 cites W2003943583 @default.
• W3215762237 cites W2013588355 @default.
• W3215762237 cites W2017051711 @default.
• W3215762237 cites W2022566075 @default.
• W3215762237 cites W2024075609 @default.
• W3215762237 cites W2030662163 @default.
• W3215762237 cites W2040424369 @default.
• W3215762237 cites W2042481895 @default.
• W3215762237 cites W2044433074 @default.
• W3215762237 cites W2045031649 @default.
• W3215762237 cites W2045302975 @default.
• W3215762237 cites W2050400197 @default.
• W3215762237 cites W2053884009 @default.
• W3215762237 cites W2064917054 @default.
• W3215762237 cites W2065169748 @default.
• W3215762237 cites W2067451258 @default.
• W3215762237 cites W2072243238 @default.
• W3215762237 cites W2077121879 @default.
• W3215762237 cites W2112304442 @default.
• W3215762237 cites W2116469627 @default.
• W3215762237 cites W2131425011 @default.
• W3215762237 cites W2132761866 @default.
• W3215762237 cites W2133277575 @default.
• W3215762237 cites W2136218557 @default.
• W3215762237 cites W2136575878 @default.
• W3215762237 cites W2159529237 @default.
• W3215762237 cites W2164835452 @default.
• W3215762237 cites W2181554613 @default.
• W3215762237 cites W2268980893 @default.
• W3215762237 cites W2293059182 @default.
• W3215762237 cites W2311134904 @default.
• W3215762237 cites W2316016196 @default.
• W3215762237 cites W2317059881 @default.
• W3215762237 cites W2318785109 @default.
• W3215762237 cites W2320028045 @default.
• W3215762237 cites W2321177716 @default.
• W3215762237 cites W2324192609 @default.
• W3215762237 cites W2325809447 @default.
• W3215762237 cites W2325903754 @default.
• W3215762237 cites W2333875011 @default.
• W3215762237 cites W2335068770 @default.
• W3215762237 cites W2342334121 @default.
• W3215762237 cites W2418701396 @default.
• W3215762237 cites W2507365567 @default.
• W3215762237 cites W2564029600 @default.
• W3215762237 cites W2570237293 @default.
• W3215762237 cites W2592852632 @default.
• W3215762237 cites W2604156473 @default.
• W3215762237 cites W2622225311 @default.
• W3215762237 cites W2685416739 @default.
• W3215762237 cites W2739823509 @default.
• W3215762237 cites W2749990257 @default.
• W3215762237 cites W2760777285 @default.
• W3215762237 cites W2766669879 @default.
• W3215762237 cites W2768240841 @default.
• W3215762237 cites W2786630066 @default.
• W3215762237 cites W2883542321 @default.
• W3215762237 cites W2891319658 @default.
• W3215762237 cites W2903250295 @default.
• W3215762237 cites W2905832666 @default.
• W3215762237 cites W2949350526 @default.
• W3215762237 cites W2951602463 @default.
• W3215762237 cites W2953343485 @default.
• W3215762237 cites W2977462078 @default.
• W3215762237 cites W2984242488 @default.
• W3215762237 cites W3002118643 @default.
• W3215762237 cites W3122384408 @default.
• W3215762237 cites W4251351998 @default.
• W3215762237 doi "https://doi.org/10.1021/acs.inorgchem.1c02589" @default.
• W3215762237 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34846129" @default.
• W3215762237 hasPublicationYear "2021" @default.
• W3215762237 type Work @default.
• W3215762237 sameAs 3215762237 @default.
• W3215762237 citedByCount "4" @default.
• W3215762237 countsByYear W32157622372022 @default.

• next