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- W3216042783 endingPage "181" @default.
- W3216042783 startingPage "141" @default.
- W3216042783 abstract "Monolayer-protected gold- and silver-based clusters (Au/Ag MPCs) have attracted increasing interests as promising building units of functional materials. Atomically precise synthesis and single-crystal X-ray diffraction analysis of Au/Ag MPCs have accelerated our understanding of the correlation between the geometric and electronic structures of the Au/Ag cores. In this chapter, we first provide a unified view of the effects of three structural factors – size, composition, and shape – of the Au/Ag cores on their electronic structures within the framework of the jellium model. The origin of the important phenomena, such as the closure of electronic shells, size-dependent evolution of the energy gaps between highest occupied molecular orbitals and lowest unoccupied molecular orbitals, and energy shift of the orbitals upon doping, is qualitatively explained by considering how the volume, depth, and shape of the jellium potential are affected by the structural factors. Then, we review both well-established and emerging methods of synthesis to precisely control the key parameters – size, shape, composition, and surface – of the chemically modified Au/Ag superatoms." @default.
- W3216042783 created "2021-12-06" @default.
- W3216042783 creator A5011230883 @default.
- W3216042783 creator A5062715723 @default.
- W3216042783 date "2021-10-29" @default.
- W3216042783 modified "2023-10-01" @default.
- W3216042783 title "Atomically Precise Synthesis of Chemically Modified Superatoms" @default.
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