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- W3216053273 abstract "A series of Gemini surfactants with an asymmetric structure (PKO 15-3(OH)-n; n = 12, 14 and 16) were synthesized through a simple two-step reaction consisting of a ring-opening reaction followed by a quaternization reaction. The surface tension measurements indicated that the surface activities of PKO 15-3(OH)-n were higher than those of traditional single-chain and symmetrical Gemini surfactants. The thermodynamic parameters obtained from electrical conductivity measurements showed that the micellization processes of PKO 15-3(OH)-n were spontaneous and entropy-driven. Transmission electron microscopy and dynamic light scattering measurements confirmed that PKO 15-3(OH)-n molecules with a higher asymmetric degree could form vesicles, in which surfactant molecules were interdigitated side-by-side in the vesicle membrane. The obtained results are not in accordance with those calculated from the critical packing theory, which can further complement the theory." @default.
- W3216053273 created "2021-12-06" @default.
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- W3216053273 date "2021-01-01" @default.
- W3216053273 modified "2023-09-25" @default.
- W3216053273 title "Synthesis, surface activities and aggregation properties of asymmetric Gemini surfactants" @default.
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- W3216053273 doi "https://doi.org/10.1039/d1cp04216e" @default.
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