Matches in SemOpenAlex for { <https://semopenalex.org/work/W3216165377> ?p ?o ?g. }
- W3216165377 endingPage "204501" @default.
- W3216165377 startingPage "204501" @default.
- W3216165377 abstract "Recent experiments have shown that the repulsive force between atomically flat, like-charged surfaces confining room-temperature ionic liquids or concentrated electrolytes exhibits an anomalously large decay length. In our previous publication [J. Zeman, S. Kondrat, and C. Holm, Chem. Commun. 56, 15635 (2020)], we showed by means of extremely large-scale molecular dynamics simulations that this so-called underscreening effect might not be a feature of bulk electrolytes. Herein, we corroborate these findings by providing additional results with more detailed analyses and expand our investigations to ionic liquids under confinement. Unlike in bulk systems, where screening lengths are computed from the decay of interionic potentials of mean force, we extract such data in confined systems from cumulative charge distributions. At high concentrations, our simulations show increasing screening lengths with increasing electrolyte concentration, consistent with classical liquid state theories. However, our analyses demonstrate that-also for confined systems-there is no anomalously large screening length. As expected, the screening lengths determined for ionic liquids under confinement are in good quantitative agreement with the screening lengths of the same ionic systems in bulk. In addition, we show that some theoretical models used in the literature to relate the measured screening lengths to other observables are inapplicable to highly concentrated electrolytes." @default.
- W3216165377 created "2021-12-06" @default.
- W3216165377 creator A5007676475 @default.
- W3216165377 creator A5016457041 @default.
- W3216165377 creator A5068509565 @default.
- W3216165377 date "2021-11-28" @default.
- W3216165377 modified "2023-10-14" @default.
- W3216165377 title "Ionic screening in bulk and under confinement" @default.
- W3216165377 cites W1031578623 @default.
- W3216165377 cites W1431264900 @default.
- W3216165377 cites W1600292521 @default.
- W3216165377 cites W1609527638 @default.
- W3216165377 cites W1624860839 @default.
- W3216165377 cites W1785190792 @default.
- W3216165377 cites W1954839759 @default.
- W3216165377 cites W1963819448 @default.
- W3216165377 cites W1966078827 @default.
- W3216165377 cites W197080977 @default.
- W3216165377 cites W1972872586 @default.
- W3216165377 cites W1981021420 @default.
- W3216165377 cites W1987543196 @default.
- W3216165377 cites W1994899946 @default.
- W3216165377 cites W1995147347 @default.
- W3216165377 cites W1995343013 @default.
- W3216165377 cites W1995574399 @default.
- W3216165377 cites W1998255271 @default.
- W3216165377 cites W2001032894 @default.
- W3216165377 cites W2001611482 @default.
- W3216165377 cites W2006186813 @default.
- W3216165377 cites W2009794731 @default.
- W3216165377 cites W2010898764 @default.
- W3216165377 cites W2019657469 @default.
- W3216165377 cites W2029667189 @default.
- W3216165377 cites W2029830270 @default.
- W3216165377 cites W2033376841 @default.
- W3216165377 cites W2034615695 @default.
- W3216165377 cites W2035687084 @default.
- W3216165377 cites W2040692275 @default.
- W3216165377 cites W2043328360 @default.
- W3216165377 cites W2044012691 @default.
- W3216165377 cites W2049475242 @default.
- W3216165377 cites W2054029467 @default.
- W3216165377 cites W2059566793 @default.
- W3216165377 cites W2059919683 @default.
- W3216165377 cites W2061089277 @default.
- W3216165377 cites W2062383224 @default.
- W3216165377 cites W2063432569 @default.
- W3216165377 cites W2064643001 @default.
- W3216165377 cites W2072419120 @default.
- W3216165377 cites W2074642780 @default.
- W3216165377 cites W2075846025 @default.
- W3216165377 cites W2079381436 @default.
- W3216165377 cites W2081799656 @default.
- W3216165377 cites W2093985678 @default.
- W3216165377 cites W2101746269 @default.
- W3216165377 cites W2113113786 @default.
- W3216165377 cites W2123768693 @default.
- W3216165377 cites W2132386582 @default.
- W3216165377 cites W2160544821 @default.
- W3216165377 cites W2170665295 @default.
- W3216165377 cites W2170711116 @default.
- W3216165377 cites W2171268876 @default.
- W3216165377 cites W2301085974 @default.
- W3216165377 cites W2329607850 @default.
- W3216165377 cites W2331209115 @default.
- W3216165377 cites W2396502916 @default.
- W3216165377 cites W2410473649 @default.
- W3216165377 cites W2423491186 @default.
- W3216165377 cites W2560124400 @default.
- W3216165377 cites W2561736514 @default.
- W3216165377 cites W2562208215 @default.
- W3216165377 cites W2580724977 @default.
- W3216165377 cites W2617784531 @default.
- W3216165377 cites W2623298656 @default.
- W3216165377 cites W2767226636 @default.
- W3216165377 cites W2767773244 @default.
- W3216165377 cites W2772607726 @default.
- W3216165377 cites W2776791428 @default.
- W3216165377 cites W2784644294 @default.
- W3216165377 cites W2788670326 @default.
- W3216165377 cites W2795044999 @default.
- W3216165377 cites W2888332271 @default.
- W3216165377 cites W2904962642 @default.
- W3216165377 cites W2930495595 @default.
- W3216165377 cites W2949523198 @default.
- W3216165377 cites W2962788551 @default.
- W3216165377 cites W2968951711 @default.
- W3216165377 cites W3004702507 @default.
- W3216165377 cites W3083844547 @default.
- W3216165377 cites W3104101921 @default.
- W3216165377 cites W3112790413 @default.
- W3216165377 cites W3126444193 @default.
- W3216165377 cites W3145685038 @default.
- W3216165377 cites W3203848370 @default.
- W3216165377 cites W4250086334 @default.
- W3216165377 doi "https://doi.org/10.1063/5.0069340" @default.
- W3216165377 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34852490" @default.
- W3216165377 hasPublicationYear "2021" @default.