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- W3216425245 endingPage "120965" @default.
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- W3216425245 abstract "Fe-N-C materials, when prepared as single-atom catalysts (SAC), display excellent activities in oxidation reactions. The systematic investigation of the iron coordination mode revealed that Fe-N4C catalysts are the most active for C-H bond oxidation. However, many of these catalysts are synthesized through pyrolysis, which is characterized by a lack of control and structures with heterogeneous composition, rarely presenting only atomically dispersed Fe−N − C as active sites. Herein, an alternative, reliable and easily reproducible method to obtain highly active Fe SACs (atomically dispersed) with Fe-N4 sites is presented, which is based on ion exchange of sodium from high crystalline sodium poly(heptazine imide) (Na-PHI) by other ions. The obtained catalyst can photocatalytically oxidize C-H bonds selectively toward ketones using only dioxygen. Detailed mechanism investigations indicate that the active species in the C-H bond oxidation are highly valent Fe(IV)/Fe(V)-oxo species, which are further activated by the holes generated at the PHI support under light irradiation." @default.
- W3216425245 created "2021-12-06" @default.
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- W3216425245 date "2022-05-01" @default.
- W3216425245 modified "2023-10-17" @default.
- W3216425245 title "Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst" @default.
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- W3216425245 cites W1981368803 @default.
- W3216425245 cites W1985935792 @default.
- W3216425245 cites W1988762313 @default.
- W3216425245 cites W2007395042 @default.
- W3216425245 cites W2011217369 @default.
- W3216425245 cites W2022307288 @default.
- W3216425245 cites W2036113194 @default.
- W3216425245 cites W2036526256 @default.
- W3216425245 cites W2047601015 @default.
- W3216425245 cites W2056866121 @default.
- W3216425245 cites W2066311520 @default.
- W3216425245 cites W2079869619 @default.
- W3216425245 cites W2083222334 @default.
- W3216425245 cites W2083343486 @default.
- W3216425245 cites W2092157292 @default.
- W3216425245 cites W2104742517 @default.
- W3216425245 cites W2120888201 @default.
- W3216425245 cites W2134716155 @default.
- W3216425245 cites W2155476546 @default.
- W3216425245 cites W2155860547 @default.
- W3216425245 cites W2174170240 @default.
- W3216425245 cites W2181522365 @default.
- W3216425245 cites W2485842556 @default.
- W3216425245 cites W2536246483 @default.
- W3216425245 cites W2542719584 @default.
- W3216425245 cites W2555576741 @default.
- W3216425245 cites W2571806585 @default.
- W3216425245 cites W2588812209 @default.
- W3216425245 cites W2678506647 @default.
- W3216425245 cites W2736999751 @default.
- W3216425245 cites W2740108463 @default.
- W3216425245 cites W2782628401 @default.
- W3216425245 cites W2786709116 @default.
- W3216425245 cites W2802648317 @default.
- W3216425245 cites W2803427589 @default.
- W3216425245 cites W2804215107 @default.
- W3216425245 cites W2808967607 @default.
- W3216425245 cites W2886912338 @default.
- W3216425245 cites W2890385237 @default.
- W3216425245 cites W2898000458 @default.
- W3216425245 cites W2898664959 @default.
- W3216425245 cites W2901912391 @default.
- W3216425245 cites W2911598292 @default.
- W3216425245 cites W2916498113 @default.
- W3216425245 cites W2929191401 @default.
- W3216425245 cites W2938839476 @default.
- W3216425245 cites W2941616776 @default.
- W3216425245 cites W2944767713 @default.
- W3216425245 cites W2947581089 @default.
- W3216425245 cites W2956043296 @default.
- W3216425245 cites W2973980246 @default.
- W3216425245 cites W2995552782 @default.
- W3216425245 cites W2997706893 @default.
- W3216425245 cites W3012977630 @default.
- W3216425245 cites W3024828156 @default.
- W3216425245 cites W3032799898 @default.
- W3216425245 cites W3082243855 @default.
- W3216425245 cites W3082518531 @default.
- W3216425245 cites W3084980168 @default.
- W3216425245 cites W3093740281 @default.
- W3216425245 cites W3093925967 @default.
- W3216425245 cites W3094658435 @default.
- W3216425245 cites W3096391660 @default.
- W3216425245 cites W3099169275 @default.
- W3216425245 cites W3108186419 @default.
- W3216425245 cites W3116267801 @default.
- W3216425245 cites W3126189997 @default.
- W3216425245 cites W3153504165 @default.
- W3216425245 cites W3165257893 @default.
- W3216425245 cites W4235255019 @default.
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- W3216425245 doi "https://doi.org/10.1016/j.apcatb.2021.120965" @default.
- W3216425245 hasPublicationYear "2022" @default.
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