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• W3216461566 abstract "Gaseous potassium (K) species released from biomass during thermochemical conversion pose challenges to reactors and human health. Photofragmentation tunable diode laser absorption spectroscopy (PF-TDLAS) was used for simultaneous, high-dynamic range measurements of atomic K, potassium hydroxide (KOH) and potassium chloride (KCl) in flat flames seeded with KCl salt. An expression for the PF-TDLAS signal is presented and experimentally verified. Axial K species concentration profiles recorded at fuel-air equivalence ratios of 0.8 and 1.3 are compared to 2D axisymmetric reacting flow simulations. An overall good agreement is found, but KOH is over-predicted in simulations of fuel-rich flames at the expense of atomic K. Quantification of K species close to softwood and wheat straw particles converted in the flames is demonstrated." @default.
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• W3216461566 date "2021-12-08" @default.
• W3216461566 modified "2023-10-17" @default.
• W3216461566 title "Simultaneous detection of K, KOH, and KCl in flames and released from biomass using photofragmentation TDLAS" @default.
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• W3216461566 doi "https://doi.org/10.1364/oe.446725" @default.
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