Matches in SemOpenAlex for { <https://semopenalex.org/work/W3216480425> ?p ?o ?g. }
- W3216480425 endingPage "133072" @default.
- W3216480425 startingPage "133072" @default.
- W3216480425 abstract "Organophosphorus flame retardants (OPFRs) have been regarded as one of the most rebarbative classes of emerging contaminants due to their persistence and toxicity. In the current study, Fe-based metal organic framework (MIL-88A) was synthesized and employed as photo-Fenton catalyst for the degradation of tris-(2-chloroisopropyl) phosphate (TCPP), a typical representative of OPFRs. The observations indicated that visible light could boost the reduction of ≡FeIII to ≡FeII in Fe-O clusters of MIL-88A during the photo-Fenton system and consequently induce the transformation of H2O2 to OH, which realized efficient degradation of TCPP. Due to the excellent function of MIL-88A, the effective pH application range of photo-Fenton system was extended in comparison with traditional Fenton system. The degradation efficiency of TCPP was visibly influenced in presence of humic acid (HA). MIL-88A exhibited a commendable reusability and stability after 3 times cycle. As the photo-Fenton reaction proceeded, TCPP was disintegrated to several kinds of carboxylated, dechlorinated and hydroxylated products. The observations of metabolomics endorsed that the interference of intermediate products mixture on E. coli weakened to a certain extent. In conclusion, carboxylation, dechlorination, hydroxylation and oxidation of TCPP were likewise effective for its detoxification, revealing that heterogeneous photo-Fenton system driven by Fe-based metal organic framework will be an attractive and safe treatment technique for OPFRs control." @default.
- W3216480425 created "2021-12-06" @default.
- W3216480425 creator A5007535808 @default.
- W3216480425 creator A5013881064 @default.
- W3216480425 creator A5054313635 @default.
- W3216480425 creator A5091878678 @default.
- W3216480425 date "2022-03-01" @default.
- W3216480425 modified "2023-10-13" @default.
- W3216480425 title "Degradation of organophosphorus flame retardants in heterogeneous photo-Fenton system driven by Fe(III)-based metal organic framework: Intermediates and their potential interference on bacterial metabolism" @default.
- W3216480425 cites W1152912451 @default.
- W3216480425 cites W1915846228 @default.
- W3216480425 cites W1964218516 @default.
- W3216480425 cites W1965064785 @default.
- W3216480425 cites W1994264434 @default.
- W3216480425 cites W1997716685 @default.
- W3216480425 cites W2008993744 @default.
- W3216480425 cites W2030625412 @default.
- W3216480425 cites W2047452146 @default.
- W3216480425 cites W2052827499 @default.
- W3216480425 cites W2055591672 @default.
- W3216480425 cites W2089153737 @default.
- W3216480425 cites W2120055287 @default.
- W3216480425 cites W2184325404 @default.
- W3216480425 cites W2289248365 @default.
- W3216480425 cites W2302530546 @default.
- W3216480425 cites W2489511853 @default.
- W3216480425 cites W2494952261 @default.
- W3216480425 cites W2522541218 @default.
- W3216480425 cites W2536519587 @default.
- W3216480425 cites W2566802392 @default.
- W3216480425 cites W2752326198 @default.
- W3216480425 cites W2765691651 @default.
- W3216480425 cites W2767155103 @default.
- W3216480425 cites W2767690247 @default.
- W3216480425 cites W2796009291 @default.
- W3216480425 cites W2797378534 @default.
- W3216480425 cites W2809952120 @default.
- W3216480425 cites W2883696489 @default.
- W3216480425 cites W2886478884 @default.
- W3216480425 cites W2922211844 @default.
- W3216480425 cites W2941984186 @default.
- W3216480425 cites W2947920767 @default.
- W3216480425 cites W2949172258 @default.
- W3216480425 cites W2951016921 @default.
- W3216480425 cites W2975587333 @default.
- W3216480425 cites W2989580273 @default.
- W3216480425 cites W2994782539 @default.
- W3216480425 cites W2995905332 @default.
- W3216480425 cites W3014632271 @default.
- W3216480425 cites W3018463907 @default.
- W3216480425 cites W3037853480 @default.
- W3216480425 cites W3039967892 @default.
- W3216480425 cites W3048499294 @default.
- W3216480425 cites W3080772054 @default.
- W3216480425 cites W3111909051 @default.
- W3216480425 cites W3133496220 @default.
- W3216480425 cites W3160476165 @default.
- W3216480425 doi "https://doi.org/10.1016/j.chemosphere.2021.133072" @default.
- W3216480425 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34838833" @default.
- W3216480425 hasPublicationYear "2022" @default.
- W3216480425 type Work @default.
- W3216480425 sameAs 3216480425 @default.
- W3216480425 citedByCount "11" @default.
- W3216480425 countsByYear W32164804252022 @default.
- W3216480425 countsByYear W32164804252023 @default.
- W3216480425 crossrefType "journal-article" @default.
- W3216480425 hasAuthorship W3216480425A5007535808 @default.
- W3216480425 hasAuthorship W3216480425A5013881064 @default.
- W3216480425 hasAuthorship W3216480425A5054313635 @default.
- W3216480425 hasAuthorship W3216480425A5091878678 @default.
- W3216480425 hasConcept C107872376 @default.
- W3216480425 hasConcept C127413603 @default.
- W3216480425 hasConcept C137981799 @default.
- W3216480425 hasConcept C161790260 @default.
- W3216480425 hasConcept C178790620 @default.
- W3216480425 hasConcept C181199279 @default.
- W3216480425 hasConcept C185592680 @default.
- W3216480425 hasConcept C199360897 @default.
- W3216480425 hasConcept C2777904410 @default.
- W3216480425 hasConcept C2779679103 @default.
- W3216480425 hasConcept C2780560099 @default.
- W3216480425 hasConcept C2780965034 @default.
- W3216480425 hasConcept C2781109383 @default.
- W3216480425 hasConcept C41008148 @default.
- W3216480425 hasConcept C42360764 @default.
- W3216480425 hasConcept C65165184 @default.
- W3216480425 hasConcept C76155785 @default.
- W3216480425 hasConcept C82685317 @default.
- W3216480425 hasConceptScore W3216480425C107872376 @default.
- W3216480425 hasConceptScore W3216480425C127413603 @default.
- W3216480425 hasConceptScore W3216480425C137981799 @default.
- W3216480425 hasConceptScore W3216480425C161790260 @default.
- W3216480425 hasConceptScore W3216480425C178790620 @default.
- W3216480425 hasConceptScore W3216480425C181199279 @default.
- W3216480425 hasConceptScore W3216480425C185592680 @default.
- W3216480425 hasConceptScore W3216480425C199360897 @default.
- W3216480425 hasConceptScore W3216480425C2777904410 @default.
- W3216480425 hasConceptScore W3216480425C2779679103 @default.