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- W3216505554 endingPage "50" @default.
- W3216505554 startingPage "50" @default.
- W3216505554 abstract "Within the cuprate constellation, one fixed star has been the superconducting dome in the quantum phase diagram of transition temperature vs. the excess charge on the Cu in the CuO2-planes, p, resulting from O-doping or cation substitution. However, a more extensive search of the literature shows that the loss of the superconductivity in favor of a normal Fermi liquid on the overdoped side should not be assumed. Many experimental results from cuprates prepared by high-pressure oxygenation show Tc converging to a fixed value or continuing to slowly increase past the upper limit of the dome of p = 0.26–0.27, up to the maximum amounts of excess oxygen corresponding to p values of 0.3 to > 0.6. These reports have been met with disinterest or disregard. Our review shows that dome-breaking trends for Tc are, in fact, the result of careful, accurate experimental work on a large number of compounds. This behavior most likely mandates a revision of the theoretical basis for high-temperature superconductivity. That excess O atoms located in specific, metastable sites in the crystal, attainable only with extreme O chemical activity under HPO conditions, cause such a radical extension of the superconductivity points to a much more substantial role for the lattice in terms of internal chemistry and bonding." @default.
- W3216505554 created "2021-12-06" @default.
- W3216505554 creator A5013346965 @default.
- W3216505554 creator A5024797419 @default.
- W3216505554 creator A5031802151 @default.
- W3216505554 creator A5036285019 @default.
- W3216505554 creator A5053207361 @default.
- W3216505554 creator A5057687816 @default.
- W3216505554 creator A5072908140 @default.
- W3216505554 creator A5086628462 @default.
- W3216505554 date "2021-12-01" @default.
- W3216505554 modified "2023-10-13" @default.
- W3216505554 title "Extremely Overdoped Superconducting Cuprates via High Pressure Oxygenation Methods" @default.
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