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• W3216840623 abstract "The reaction of [{(Arnacnac)Mg}2] (Arnacnac = HC{MeC(NAr)}2, Ar = 2,6-diisopropylphenyl, Dip, or 2,6-diethylphenyl, Dep) with 4-dimethylaminopyridine (DMAP) at elevated temperatures afforded the hexameric magnesium 4-pyridyl complex [{(Arnacnac)Mg(4-C5H4N)}6] via reductive cleavage of the DMAP C-N bond. The title compound contains a large s-block organometallic cyclohexane-like ring structure comprising tetrahedral (Arnacnac)Mg nodes and linked by linear 4-pyridyl bridging ligands, and the structure is compared with other ring systems. [(Dipnacnac)Mg(DMAP)(NMe2)] was structurally characterised as a by-product." @default.
• W3216840623 created "2021-12-06" @default.
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• W3216840623 date "2021-11-28" @default.
• W3216840623 modified "2023-09-24" @default.
• W3216840623 title "Synthesis of a Hexameric Magnesium 4-pyridyl Complex with Cyclohexane-like Ring Structure via Reductive C-N Activation" @default.
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• W3216840623 doi "https://doi.org/10.3390/molecules26237214" @default.
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