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- W3216942016 abstract "Abstract A simple, practical, and high chemo-selective method for the synthesis of propargyl alcohol and allenyl alcohols via Cu-catalyzed, Mn-mediated propargylation and allenylation of aldehydes with propargyl bromides has been established. When 3-bromo-1-propyne was conducted under the standard condition, the aldehydes were transformed to the corresponding propargylation products completely, while when 1-bromo-2-pentyne was used, allenic alcohol was the only product. Variety of homopropargyl alcohols and allenyl alcohols were obtained in high yields and the reaction is compatible with broad substrate scopes. In addition, the large-scale reaction could also be proceeded smoothly indicating the potential synthetic applications of this transformation." @default.
- W3216942016 created "2021-12-06" @default.
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- W3216942016 date "2021-11-24" @default.
- W3216942016 modified "2023-10-14" @default.
- W3216942016 title "Cu-Catalyzed, Mn-Mediated Propargylation and Allenylation of Aldehydes with Propargyl Bromides" @default.
- W3216942016 doi "https://doi.org/10.21203/rs.3.rs-1080113/v1" @default.
- W3216942016 hasPublicationYear "2021" @default.
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