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- W3217008286 abstract "Here, we report the photophysical structure-property relationship of porphyrins adsorbed on gold nanoparticles. The number of porphyrin-alkanethiolate adsorbates per particle was adjusted by a post-synthetic thiol/thiolate exchange reaction on 1-dodecanethiolate-protected gold nanoparticles. Even with a low loading level of adsorbates (<10% of all thiolate sites on gold nanoparticles), the shoulder absorption at the Soret band was intensified, indicating the formation of aggregates of porphyrin adsorbates on the nanoparticles. Steady-state fluorescence quantum yields could be adjusted by the bulkiness of substituents at the meso-positions of the porphyrin or the methylene linker chain length, regardless of the porphyrin loading level and the nanoparticle diameter." @default.
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- W3217008286 date "2021-11-23" @default.
- W3217008286 modified "2023-10-18" @default.
- W3217008286 title "Porphyrin Photoabsorption and Fluorescence Variation with Adsorptive Loading on Gold Nanoparticles" @default.
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- W3217008286 doi "https://doi.org/10.3389/fchem.2021.777041" @default.
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