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- W321713049 abstract "In this paper we present the results of our mass spectrometric investigations for Van der Waals clusters of 2-methoxyethanol and 2-ethoxyethanol. The cluster mass spectra were acquired for a variety of expansion conditions and electron energies. The protonated alkoxyethanol cluster ions (AE) nH(+) form the dominant cluster ion series. A number of fragment ions, that may arise from an unprotonated and/or a protonated alkoxyethanol molecular ion, were solvated by additional alkoxyethanol molecules. The (AE)n(H20)mH(+) ions were observed with significant intensities only for n >/= 5 in neat as well as mixed alkoxyethanol/water expansions. It was also found that (AE) n (H2O)mH(+) cluster ions which satisfy the condition n = 2 (m + 2), for m = 1 and 2, have enhanced ion intensities. The various models that may explain the behavior of (AE)n(H2O)mH(+) are discussed." @default.
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- W321713049 date "1993-04-03" @default.
- W321713049 modified "2023-09-27" @default.
- W321713049 title "Mass spectrometric investigation of 2-methoxyethanol and 2-ethoxyethanol clusters: Magic numbers and structural implications. Technical report" @default.
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