FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3217309054> ?p ?o ?g. }

• W3217309054 endingPage "99" @default.
• W3217309054 startingPage "91" @default.
• W3217309054 abstract "In this paper we report the design of hybrid reaction centers with a novel redox-active cofactor. Reaction centers perform the primary photochemistry of photosynthesis, namely the light-induced transfer of an electron from the bacteriochlorophyll dimer to a series of electron acceptors. Hybrid complexes were created by the fusion of an artificial four-helix bundle to the M-subunit of the reaction center. Despite the large modification, optical spectra show that the purified hybrid reaction centers assemble as active complexes that retain the characteristic cofactor absorption peaks and are capable of light-induced charge separation. The four-helix bundle could bind iron-protoporphyrin in either a reduced and oxidized state. After binding iron-protoporphyrin to the hybrid reaction centers, light excitation results in a new derivative signal with a maximum at 402 nm and minimum at 429 nm. This signal increases in amplitude with longer light durations and persists in the dark. No signal is observed when iron-protoporphyrin is added to reaction centers without the four-helix bundle domain or when a redox-inactive zinc-protoporphyrin is bound. The results are consistent with the signal arising from a new redox reaction, electron transfer from the iron-protoporphyrin to the oxidized bacteriochlorophyll dimer. These outcomes demonstrate the feasibility of binding porphyrins to the hybrid reaction centers to gain new light-driven functions." @default.
• W3217309054 created "2021-12-06" @default.
• W3217309054 creator A5023014150 @default.
• W3217309054 creator A5025111294 @default.
• W3217309054 creator A5057709120 @default.
• W3217309054 creator A5084478928 @default.
• W3217309054 date "2021-11-30" @default.
• W3217309054 modified "2023-10-02" @default.
• W3217309054 title "A bound iron porphyrin is redox active in hybrid bacterial reaction centers modified to possess a four-helix bundle domain" @default.
• W3217309054 cites W1498515556 @default.
• W3217309054 cites W152281125 @default.
• W3217309054 cites W1787348572 @default.
• W3217309054 cites W1916034164 @default.
• W3217309054 cites W1963741258 @default.
• W3217309054 cites W1972521965 @default.
• W3217309054 cites W1973614655 @default.
• W3217309054 cites W1976236461 @default.
• W3217309054 cites W1977874378 @default.
• W3217309054 cites W1980032355 @default.
• W3217309054 cites W1985440805 @default.
• W3217309054 cites W1989270637 @default.
• W3217309054 cites W2001611902 @default.
• W3217309054 cites W2007053101 @default.
• W3217309054 cites W2008279485 @default.
• W3217309054 cites W2020646508 @default.
• W3217309054 cites W2020719323 @default.
• W3217309054 cites W2021075287 @default.
• W3217309054 cites W2024156372 @default.
• W3217309054 cites W2024296243 @default.
• W3217309054 cites W2029449965 @default.
• W3217309054 cites W2032281682 @default.
• W3217309054 cites W2041395494 @default.
• W3217309054 cites W2058376614 @default.
• W3217309054 cites W2063780436 @default.
• W3217309054 cites W2071993181 @default.
• W3217309054 cites W2080798293 @default.
• W3217309054 cites W2083114864 @default.
• W3217309054 cites W2092978809 @default.
• W3217309054 cites W2100865709 @default.
• W3217309054 cites W2102028493 @default.
• W3217309054 cites W2118539842 @default.
• W3217309054 cites W2124382146 @default.
• W3217309054 cites W2126036997 @default.
• W3217309054 cites W2130939465 @default.
• W3217309054 cites W2176126080 @default.
• W3217309054 cites W2331937820 @default.
• W3217309054 cites W2415839340 @default.
• W3217309054 cites W2433650340 @default.
• W3217309054 cites W2518493009 @default.
• W3217309054 cites W2519539312 @default.
• W3217309054 cites W2569067286 @default.
• W3217309054 cites W2586899807 @default.
• W3217309054 cites W2750713052 @default.
• W3217309054 cites W2751743037 @default.
• W3217309054 cites W2769714992 @default.
• W3217309054 cites W2889086095 @default.
• W3217309054 cites W2902877684 @default.
• W3217309054 cites W2911475376 @default.
• W3217309054 cites W2920482566 @default.
• W3217309054 cites W2935887612 @default.
• W3217309054 cites W2982008318 @default.
• W3217309054 cites W3013871991 @default.
• W3217309054 cites W3116660244 @default.
• W3217309054 cites W73097751 @default.
• W3217309054 doi "https://doi.org/10.1007/s43630-021-00142-7" @default.
• W3217309054 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34850374" @default.
• W3217309054 hasPublicationYear "2021" @default.
• W3217309054 type Work @default.
• W3217309054 sameAs 3217309054 @default.
• W3217309054 citedByCount "0" @default.
• W3217309054 crossrefType "journal-article" @default.
• W3217309054 hasAuthorship W3217309054A5023014150 @default.
• W3217309054 hasAuthorship W3217309054A5025111294 @default.
• W3217309054 hasAuthorship W3217309054A5057709120 @default.
• W3217309054 hasAuthorship W3217309054A5084478928 @default.
• W3217309054 hasBestOaLocation W32173090541 @default.
• W3217309054 hasConcept C123669783 @default.
• W3217309054 hasConcept C178790620 @default.
• W3217309054 hasConcept C179104552 @default.
• W3217309054 hasConcept C181199279 @default.
• W3217309054 hasConcept C183688256 @default.
• W3217309054 hasConcept C185592680 @default.
• W3217309054 hasConcept C188231169 @default.
• W3217309054 hasConcept C2776217839 @default.
• W3217309054 hasConcept C2778417259 @default.
• W3217309054 hasConcept C2779480358 @default.
• W3217309054 hasConcept C2779546866 @default.
• W3217309054 hasConcept C2780784151 @default.
• W3217309054 hasConcept C55493867 @default.
• W3217309054 hasConcept C55904794 @default.
• W3217309054 hasConcept C75473681 @default.
• W3217309054 hasConceptScore W3217309054C123669783 @default.
• W3217309054 hasConceptScore W3217309054C178790620 @default.
• W3217309054 hasConceptScore W3217309054C179104552 @default.
• W3217309054 hasConceptScore W3217309054C181199279 @default.
• W3217309054 hasConceptScore W3217309054C183688256 @default.
• W3217309054 hasConceptScore W3217309054C185592680 @default.
• W3217309054 hasConceptScore W3217309054C188231169 @default.

• next