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• W3217364047 abstract "The decarbonylation of a cage-opened C60 derivative was examined by employing single-electron reductants. During the reaction, an H2O molecule was spontaneously encapsulated inside the cage (up to 78%) through the thus-formed 14-membered-ring orifice even though the H2O encapsulation had long been considered to require an orifice consisting of at least 16 atoms. The crystallographic analysis revealed an orifice shape closer to a circle which significantly contributes to the decreased activation barrier for the H2O encapsulation." @default.
• W3217364047 created "2021-12-06" @default.
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• W3217364047 date "2021-11-22" @default.
• W3217364047 modified "2023-10-15" @default.
• W3217364047 title "Reductive Decarbonylation of a Cage-Opened C₆₀ Derivative" @default.
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• W3217364047 doi "https://doi.org/10.1021/acs.orglett.1c03694" @default.
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