Matches in SemOpenAlex for { <https://semopenalex.org/work/W3217488730> ?p ?o ?g. }
- W3217488730 endingPage "21126" @default.
- W3217488730 startingPage "21113" @default.
- W3217488730 abstract "Predicting wavelength-dependent photochemical reactivity is challenging. Herein, we revive the well-established tool of measuring action spectra and adapt the technique to map wavelength-resolved covalent bond formation and cleavage in what we term photochemical action plots. Underpinned by tunable lasers, which allow excitation of molecules with near-perfect wavelength precision, the photoinduced reactivity of several reaction classes have been mapped in detail. These include photoinduced cycloadditions and bond formation based on photochemically generated o-quinodimethanes and 1,3-dipoles such as nitrile imines as well as radical photoinitiator cleavage. Organized by reaction class, these data demonstrate that UV/vis spectra fail to act as a predictor for photochemical reactivity at a given wavelength in most of the examined reactions, with the photochemical reactivity being strongly red shifted in comparison to the absorption spectrum. We provide an encompassing perspective of the power of photochemical action plots for bond-forming reactions and their emerging applications in the design of wavelength-selective photoresists and photoresponsive soft-matter materials." @default.
- W3217488730 created "2021-12-06" @default.
- W3217488730 creator A5004482996 @default.
- W3217488730 creator A5013278579 @default.
- W3217488730 creator A5026999169 @default.
- W3217488730 creator A5032574718 @default.
- W3217488730 creator A5038468402 @default.
- W3217488730 creator A5067740531 @default.
- W3217488730 creator A5080205224 @default.
- W3217488730 date "2021-12-03" @default.
- W3217488730 modified "2023-10-11" @default.
- W3217488730 title "Action Plots in Action: In-Depth Insights into Photochemical Reactivity" @default.
- W3217488730 cites W1587510658 @default.
- W3217488730 cites W1836441987 @default.
- W3217488730 cites W1964491821 @default.
- W3217488730 cites W1966763936 @default.
- W3217488730 cites W1968113189 @default.
- W3217488730 cites W1968344694 @default.
- W3217488730 cites W1970895524 @default.
- W3217488730 cites W1975247969 @default.
- W3217488730 cites W1979590563 @default.
- W3217488730 cites W1983171843 @default.
- W3217488730 cites W1984874582 @default.
- W3217488730 cites W1993909252 @default.
- W3217488730 cites W1998011034 @default.
- W3217488730 cites W1999490106 @default.
- W3217488730 cites W2000877542 @default.
- W3217488730 cites W2001533266 @default.
- W3217488730 cites W2002163358 @default.
- W3217488730 cites W2004374984 @default.
- W3217488730 cites W2005126509 @default.
- W3217488730 cites W2014444464 @default.
- W3217488730 cites W2017458967 @default.
- W3217488730 cites W2018539827 @default.
- W3217488730 cites W2018998026 @default.
- W3217488730 cites W2021188145 @default.
- W3217488730 cites W2023979506 @default.
- W3217488730 cites W2028054272 @default.
- W3217488730 cites W2033340645 @default.
- W3217488730 cites W2038024406 @default.
- W3217488730 cites W2042643142 @default.
- W3217488730 cites W2062586008 @default.
- W3217488730 cites W2063397125 @default.
- W3217488730 cites W2063625749 @default.
- W3217488730 cites W2063764814 @default.
- W3217488730 cites W2067957471 @default.
- W3217488730 cites W2076360604 @default.
- W3217488730 cites W2080322937 @default.
- W3217488730 cites W2082242154 @default.
- W3217488730 cites W2089229441 @default.
- W3217488730 cites W2097578667 @default.
- W3217488730 cites W2105487561 @default.
- W3217488730 cites W2112004907 @default.
- W3217488730 cites W2115203821 @default.
- W3217488730 cites W2115908598 @default.
- W3217488730 cites W2122404351 @default.
- W3217488730 cites W2131054969 @default.
- W3217488730 cites W2134491231 @default.
- W3217488730 cites W2140884457 @default.
- W3217488730 cites W2141055446 @default.
- W3217488730 cites W2142721422 @default.
- W3217488730 cites W2146542638 @default.
- W3217488730 cites W2146749522 @default.
- W3217488730 cites W2157801527 @default.
- W3217488730 cites W2178247027 @default.
- W3217488730 cites W2286945148 @default.
- W3217488730 cites W2308236640 @default.
- W3217488730 cites W2314782050 @default.
- W3217488730 cites W2320460250 @default.
- W3217488730 cites W2330906567 @default.
- W3217488730 cites W2398660212 @default.
- W3217488730 cites W2438676060 @default.
- W3217488730 cites W2462930808 @default.
- W3217488730 cites W2550550978 @default.
- W3217488730 cites W2552446700 @default.
- W3217488730 cites W2558839892 @default.
- W3217488730 cites W2563361423 @default.
- W3217488730 cites W2592634495 @default.
- W3217488730 cites W2598394266 @default.
- W3217488730 cites W2618596241 @default.
- W3217488730 cites W2620795683 @default.
- W3217488730 cites W2750247622 @default.
- W3217488730 cites W2761643084 @default.
- W3217488730 cites W2762006196 @default.
- W3217488730 cites W2767618823 @default.
- W3217488730 cites W2783402247 @default.
- W3217488730 cites W2801556762 @default.
- W3217488730 cites W2810626283 @default.
- W3217488730 cites W2886273927 @default.
- W3217488730 cites W2888473089 @default.
- W3217488730 cites W2892023500 @default.
- W3217488730 cites W2910654870 @default.
- W3217488730 cites W2911564119 @default.
- W3217488730 cites W2916842729 @default.
- W3217488730 cites W2917736247 @default.
- W3217488730 cites W2925297077 @default.
- W3217488730 cites W2967609396 @default.
- W3217488730 cites W2971747708 @default.