Matches in SemOpenAlex for { <https://semopenalex.org/work/W3217503486> ?p ?o ?g. }
- W3217503486 endingPage "133897" @default.
- W3217503486 startingPage "133897" @default.
- W3217503486 abstract "• A new metal–organic framework (MOF) was built using symmetrical TADF unit. • A high photoreduction rate of CO 2 was achieved up to 50 ummol g -1 h −1 . • In situ EPR spectra has revealed the active metal site. • The D-A unit assisted in dramatical increase of photocathode in photoreduction. • The TADF-MOF works as an integrated photocatalyst in CO 2 photoreduction. The performance of metal–organic-framework-based photocatalysts were usually limited by the short lifetime of excited state and the high cost of precious metal complexes in CO 2 photoreduction. To enhance the lifetime of excited state, an organic thermally activated delayed fluorescence photosensitizer was installed with the non-noble zinc node in a periodic structure named Spiro-Zn-MOF. The horizontally prolonged linker based on D-A (D: Donor, A: Acceptor) unit provided a delayed lifetime up to micro-second-level lifetime for excited state, which was inherited in the Spiro-Zn-MOF. And the inborn D-A structure of Spiro-Zn-MOF worked with zinc node in a synergistic way, leading to a large photocathode current in the scaffold allowing for high photoreduction rate. Combination of long-lived excited state and efficient charge transfer in noble-metal-free D-A unit allowed for efficient CO 2 photoreduction with a production rate of CO up to almost 50 μmol h −1 g −1 , which far exceeded the performances of zinc-based MOF-5 and commercialized TiO 2 (P25) under the same conditions." @default.
- W3217503486 created "2021-12-06" @default.
- W3217503486 creator A5068254077 @default.
- W3217503486 creator A5071048627 @default.
- W3217503486 creator A5078457425 @default.
- W3217503486 creator A5087266984 @default.
- W3217503486 creator A5089900071 @default.
- W3217503486 date "2022-03-01" @default.
- W3217503486 modified "2023-10-14" @default.
- W3217503486 title "Long Excited State Lifetime of Thermally Activated Delayed Fluorescent Photosensitizer Integrated into Metal-organic Framework Enables Efficient CO2 Photoreduction" @default.
- W3217503486 cites W1970393749 @default.
- W3217503486 cites W1976269136 @default.
- W3217503486 cites W1996941025 @default.
- W3217503486 cites W2015840697 @default.
- W3217503486 cites W2046583887 @default.
- W3217503486 cites W2051796629 @default.
- W3217503486 cites W2080606770 @default.
- W3217503486 cites W2100253757 @default.
- W3217503486 cites W2113310175 @default.
- W3217503486 cites W2126674309 @default.
- W3217503486 cites W2170115420 @default.
- W3217503486 cites W2504256884 @default.
- W3217503486 cites W2582344271 @default.
- W3217503486 cites W2733344830 @default.
- W3217503486 cites W2754630493 @default.
- W3217503486 cites W2762255780 @default.
- W3217503486 cites W2777629503 @default.
- W3217503486 cites W2783183401 @default.
- W3217503486 cites W2792288416 @default.
- W3217503486 cites W2808651797 @default.
- W3217503486 cites W2890194264 @default.
- W3217503486 cites W2895338435 @default.
- W3217503486 cites W2940492351 @default.
- W3217503486 cites W2940888224 @default.
- W3217503486 cites W2963049339 @default.
- W3217503486 cites W2965766478 @default.
- W3217503486 cites W2969272557 @default.
- W3217503486 cites W2997279900 @default.
- W3217503486 cites W3034927264 @default.
- W3217503486 cites W3081604959 @default.
- W3217503486 cites W3083910900 @default.
- W3217503486 cites W3094014759 @default.
- W3217503486 cites W3135582459 @default.
- W3217503486 cites W4211024534 @default.
- W3217503486 cites W2963588652 @default.
- W3217503486 doi "https://doi.org/10.1016/j.cej.2021.133897" @default.
- W3217503486 hasPublicationYear "2022" @default.
- W3217503486 type Work @default.
- W3217503486 sameAs 3217503486 @default.
- W3217503486 citedByCount "7" @default.
- W3217503486 countsByYear W32175034862022 @default.
- W3217503486 countsByYear W32175034862023 @default.
- W3217503486 crossrefType "journal-article" @default.
- W3217503486 hasAuthorship W3217503486A5068254077 @default.
- W3217503486 hasAuthorship W3217503486A5071048627 @default.
- W3217503486 hasAuthorship W3217503486A5078457425 @default.
- W3217503486 hasAuthorship W3217503486A5087266984 @default.
- W3217503486 hasAuthorship W3217503486A5089900071 @default.
- W3217503486 hasConcept C120665830 @default.
- W3217503486 hasConcept C121332964 @default.
- W3217503486 hasConcept C13115443 @default.
- W3217503486 hasConcept C147120987 @default.
- W3217503486 hasConcept C161790260 @default.
- W3217503486 hasConcept C178790620 @default.
- W3217503486 hasConcept C181500209 @default.
- W3217503486 hasConcept C184779094 @default.
- W3217503486 hasConcept C185592680 @default.
- W3217503486 hasConcept C192562407 @default.
- W3217503486 hasConcept C26873012 @default.
- W3217503486 hasConcept C2775871042 @default.
- W3217503486 hasConcept C2779892579 @default.
- W3217503486 hasConcept C2781469039 @default.
- W3217503486 hasConcept C535196362 @default.
- W3217503486 hasConcept C544153396 @default.
- W3217503486 hasConcept C62520636 @default.
- W3217503486 hasConcept C65165184 @default.
- W3217503486 hasConcept C75473681 @default.
- W3217503486 hasConcept C91881484 @default.
- W3217503486 hasConceptScore W3217503486C120665830 @default.
- W3217503486 hasConceptScore W3217503486C121332964 @default.
- W3217503486 hasConceptScore W3217503486C13115443 @default.
- W3217503486 hasConceptScore W3217503486C147120987 @default.
- W3217503486 hasConceptScore W3217503486C161790260 @default.
- W3217503486 hasConceptScore W3217503486C178790620 @default.
- W3217503486 hasConceptScore W3217503486C181500209 @default.
- W3217503486 hasConceptScore W3217503486C184779094 @default.
- W3217503486 hasConceptScore W3217503486C185592680 @default.
- W3217503486 hasConceptScore W3217503486C192562407 @default.
- W3217503486 hasConceptScore W3217503486C26873012 @default.
- W3217503486 hasConceptScore W3217503486C2775871042 @default.
- W3217503486 hasConceptScore W3217503486C2779892579 @default.
- W3217503486 hasConceptScore W3217503486C2781469039 @default.
- W3217503486 hasConceptScore W3217503486C535196362 @default.
- W3217503486 hasConceptScore W3217503486C544153396 @default.
- W3217503486 hasConceptScore W3217503486C62520636 @default.
- W3217503486 hasConceptScore W3217503486C65165184 @default.
- W3217503486 hasConceptScore W3217503486C75473681 @default.
- W3217503486 hasConceptScore W3217503486C91881484 @default.