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• W3217593351 abstract "By their conformational flexibility, Möbius aromatic hexaphyrins provide a dynamic chirality attractive to develop stimuli responsive systems such as chiroptical switches. A regular [28]hexaphyrin has been equipped with a chiral coordinating arm to achieve transfer of chirality from a fix stereogenic element to the dynamic Möbius one. The arm allows straightforward formation of labile monometallic ZnII complexes with an exogenous ligand, either a carboxylato or an amino with opposite inwards/outwards orientations relative to the Möbius ring. As a corollary, the chiral coordinating arm is constrained over the ring or laterally, inducing opposite P and M Möbius configurations with unprecedented high stereoselectivity (diast. excess greater than 95 %). By tuning the transfer of chirality, these achiral effectors generate electronic circular dichroism spectra with bisignate Cotton effect of opposite signs. Switching between distinct chiroptical states was ultimately achieved in mild conditions owing to ligand exchange, with high robustness (10 cycles)." @default.
• W3217593351 created "2021-12-06" @default.
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• W3217593351 date "2021-12-20" @default.
• W3217593351 modified "2023-09-26" @default.
• W3217593351 title "Möbius Zn^II‐Hexaphyrins Bearing a Chiral Coordinating Arm: A Chiroptical Switch Featuring P/M Twist Inversion Controlled by Achiral Effectors" @default.
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• W3217593351 doi "https://doi.org/10.1002/anie.202113844" @default.
• W3217593351 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34813138" @default.
• W3217593351 hasPublicationYear "2021" @default.
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