Matches in SemOpenAlex for { <https://semopenalex.org/work/W3217598340> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W3217598340 abstract "Energy transfer and spatial diffusion are two significant sub-processes in chemical reaction. Traditional rate theory is based on two assumptions: (1) energy transfer is faster than chemical reaction so that specific energy transfer channel is not important. (2) The solvents can respond to the change of solute quickly resulting in equilibrium solvation. Then once system cross the barrier, it will enter the product basin. But when energy transfer is fast enough to distribute the energy into all degrees of freedom according to certain ratio, the specific energy transfer pathways should be considered. Our previous studies have found that the polar functional groups play the major role in the intermolecular energy transfer process. And the energy accumulation and dissipation are completed by the motion with specific frequency. Furthermore, the major energy transfer channel is different in different solutions. Moreover, the length of transition path is very short, leading to the existence of different transient solvation configurations with distinctly different strengths of interaction between solutes and solvents. Consequently, the motion of solvents modulates the reaction dynamics and results in heterogeneous reaction paths. Therefore, the dynamic effects are vital for understanding and controlling the chemical reaction." @default.
- W3217598340 created "2021-12-06" @default.
- W3217598340 creator A5044948594 @default.
- W3217598340 creator A5045839676 @default.
- W3217598340 creator A5064593519 @default.
- W3217598340 creator A5071672663 @default.
- W3217598340 date "2020-09-14" @default.
- W3217598340 modified "2023-10-16" @default.
- W3217598340 title "The importance of dynamic effects in chemical reactions in condensed phase" @default.
- W3217598340 doi "https://doi.org/10.1360/ssc-2020-0105" @default.
- W3217598340 hasPublicationYear "2020" @default.
- W3217598340 type Work @default.
- W3217598340 sameAs 3217598340 @default.
- W3217598340 citedByCount "0" @default.
- W3217598340 crossrefType "journal-article" @default.
- W3217598340 hasAuthorship W3217598340A5044948594 @default.
- W3217598340 hasAuthorship W3217598340A5045839676 @default.
- W3217598340 hasAuthorship W3217598340A5064593519 @default.
- W3217598340 hasAuthorship W3217598340A5071672663 @default.
- W3217598340 hasBestOaLocation W32175983401 @default.
- W3217598340 hasConcept C121332964 @default.
- W3217598340 hasConcept C135402231 @default.
- W3217598340 hasConcept C148093993 @default.
- W3217598340 hasConcept C159467904 @default.
- W3217598340 hasConcept C161790260 @default.
- W3217598340 hasConcept C166950319 @default.
- W3217598340 hasConcept C175113610 @default.
- W3217598340 hasConcept C177801218 @default.
- W3217598340 hasConcept C178790620 @default.
- W3217598340 hasConcept C185592680 @default.
- W3217598340 hasConcept C186370098 @default.
- W3217598340 hasConcept C22547674 @default.
- W3217598340 hasConcept C32909587 @default.
- W3217598340 hasConcept C62520636 @default.
- W3217598340 hasConcept C69357855 @default.
- W3217598340 hasConcept C82160515 @default.
- W3217598340 hasConcept C97355855 @default.
- W3217598340 hasConceptScore W3217598340C121332964 @default.
- W3217598340 hasConceptScore W3217598340C135402231 @default.
- W3217598340 hasConceptScore W3217598340C148093993 @default.
- W3217598340 hasConceptScore W3217598340C159467904 @default.
- W3217598340 hasConceptScore W3217598340C161790260 @default.
- W3217598340 hasConceptScore W3217598340C166950319 @default.
- W3217598340 hasConceptScore W3217598340C175113610 @default.
- W3217598340 hasConceptScore W3217598340C177801218 @default.
- W3217598340 hasConceptScore W3217598340C178790620 @default.
- W3217598340 hasConceptScore W3217598340C185592680 @default.
- W3217598340 hasConceptScore W3217598340C186370098 @default.
- W3217598340 hasConceptScore W3217598340C22547674 @default.
- W3217598340 hasConceptScore W3217598340C32909587 @default.
- W3217598340 hasConceptScore W3217598340C62520636 @default.
- W3217598340 hasConceptScore W3217598340C69357855 @default.
- W3217598340 hasConceptScore W3217598340C82160515 @default.
- W3217598340 hasConceptScore W3217598340C97355855 @default.
- W3217598340 hasLocation W32175983401 @default.
- W3217598340 hasOpenAccess W3217598340 @default.
- W3217598340 hasPrimaryLocation W32175983401 @default.
- W3217598340 hasRelatedWork W17694217 @default.
- W3217598340 hasRelatedWork W20006780 @default.
- W3217598340 hasRelatedWork W22562710 @default.
- W3217598340 hasRelatedWork W27555761 @default.
- W3217598340 hasRelatedWork W3250196 @default.
- W3217598340 hasRelatedWork W32759696 @default.
- W3217598340 hasRelatedWork W3317631 @default.
- W3217598340 hasRelatedWork W35511324 @default.
- W3217598340 hasRelatedWork W35799472 @default.
- W3217598340 hasRelatedWork W4385847 @default.
- W3217598340 isParatext "false" @default.
- W3217598340 isRetracted "false" @default.
- W3217598340 magId "3217598340" @default.
- W3217598340 workType "article" @default.