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- W3217698663 abstract "Copper hexadecafluorophthalocyanine (CuFPc) has excellent environmental and thermal stability and stable n-type semiconducting properties under ambient conditions. We investigated the exciton diffusion dynamics in individual CuFPc single-crystalline nanorods having the width of 20–40 nm and the length of 100–1000 nm by femtosecond pump and probe single-nanoparticle spectroscopy. The excitation intensity dependence of the excited-state decay profiles was examined for 38 single nanorods. The exciton diffusion coefficient in a one-dimensional (1D) stack of CuFPc molecules in a single nanorod was estimated from the rate constant of exciton–exciton bimolecular annihilation. It was found that the values of the exciton diffusion coefficient were scattered in the range of 0.001–0.08 cm2 s–1 and showed a correlation with the resonance peak wavelengths and widths of the exciton transition of the nanorods. These results indicated that the exciton diffusion coefficient was dependent on the length of the nanorod and became large in shorter-length nanorods." @default.
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- W3217698663 date "2021-12-02" @default.
- W3217698663 modified "2023-10-16" @default.
- W3217698663 title "Femtosecond Pump-Probe, Single-Particle Spectroscopic Study on Excited-State Migration Dynamics of Copper Hexadecafluorophthalocyanine Nanorods" @default.
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- W3217698663 doi "https://doi.org/10.1021/acs.jpcc.1c06785" @default.
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