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- W325536595 abstract "It is usually considered that nonpolar alkyl substituents do not interact with other sufficiently distant groups. Therefore, the introduction of a methyl group into the molecule is sometimes used as a means for displacing the conformational equilibria of substituted cyclohexanes by a strictly defined amount. The authors have checked the accuracy of such an approach by comparing the conformational equilibria of trans-1,2-dimethoxycyclohexane and 1r,2t-dimethoxy-4c-methylcyclohexane. The ratio of the conformers was established by measuring the integral intensities of their signals in the low-temperature /sup 13/C NMR spectra. The spectra were measured on a Varian FT-70 spectrometer at 20 MHz with /sup 13/C-//sup 1/H/ proton decoupling." @default.
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- W325536595 date "1987-10-20" @default.
- W325536595 modified "2023-09-24" @default.
- W325536595 title "Conformational characteristics of 1r,2t-dimethoxy-4c-methylcyclohexane. The nonadditivity of the conformational energy of the methyl group" @default.
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