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- W325818491 abstract "The decay reactions of N,N-dimethyl-p-anisidine (DMA) cation radical (DMA . + ) in acetonitrile (AN) have been analysed using an electron transfer stopped-flow (ETSF) method. In the ETSF method, DMA . + is generated by mixing acetonitrile solutions of DMA and tris(p-bromophenyl)amine cation radical (TBPA . + ). While DMA . + is fairly stable without DMA, the decay reactions of DMA . + have been observed when DMA remained in a large excess with DMA . + in acetonitrile. Such promotion of the decay reaction is similar to the reactions of N,N-dimethyl-p-toluidine (DMT) cation radical (DMT . + ). which we have analysed previously. The rate law determined for the reaction of DMA . + with DMA, -d[DMA . + ]/dr = k [DMA . + ] [DMA] (k =8.05 M - 1 s - 1 ), indicates that the reaction mechanism is similar to that of DMT - 1 . By analysing the reactions of DMA . + with pyridine, it has been confirmed that the reaction mechanism proceeds via the acid-base interaction." @default.
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- W325818491 date "2003-04-01" @default.
- W325818491 modified "2023-09-25" @default.
- W325818491 title "Spectroelectrochemical approach for analysing the reaction kinetics of N, N-dimethyl-p-anisidine cation radical with the neutral molecule in acetonitrile" @default.
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