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- W328540341 abstract "A new, feasible procedure for high-precision bromine isotope analysis using multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) is described. With a combination of HR mass resolution mode and accurate optimization of the Zoom Optics parameters (Focus Quad: -1.30; Zoom Quad: 0.00), the challenging problem of the isobaric interferences ((40)Ar(38)ArH(+) and (40)Ar(40)ArH(+)) in the measurement of bromine isotopes ((79)Br(+), (81)Br(+)) has been effectively solved. The external reproducibility of the measured (81)Br/(79)Br ratios in the selected standard reference materials ranged from ±0.03‰ to ±0.14‰, which is superior to or equivalent to the best results from previous contributions. The effect of counter cations on the Br(+) signal intensity and the instrumental-induced mass bias was evaluated as the loss of HBr aerosol in nebulizer and potential diffusive isotope fractionations." @default.
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- W328540341 date "2015-10-01" @default.
- W328540341 modified "2023-10-17" @default.
- W328540341 title "Improvements on high-precision measurement of bromine isotope ratios by multicollector inductively coupled plasma mass spectrometry" @default.
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- W328540341 doi "https://doi.org/10.1016/j.talanta.2015.04.073" @default.
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