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- W32876170 abstract "This chapter focuses on the effects of water vapor on oxidation. The nature of the problem is illustrated, where the results of oxidizing a ferritic 9% Cr steel at 650°C in N2/O2 and N2/O2/H2O are compared. The dry gas produce an extremely thin scale with a chromium-rich layer adjacent to the alloy, and protective behavior is achieved. The mechanisms whereby water vapor changes the phase constitution, microstructure and growth rate of the oxidation product are of both fundamental interest and practical importance. Atmospheric air contains water vapor at levels, which vary with temperature and relative humidity. Water vapor is invariably a constituent of combustion gases, and can therefore affect corrosion in engines, direct fired furnaces, and recuperators. Pure steam is the working fluid in many power generating systems, as well as being handled as a process stream in a diversity of chemical plants. Water vapor can, in principle, interact with an oxidizing metal in a number of ways. It can participate in surface reactions, thereby modifying the scale–gas interface or even producing volatile hydrated species. It can interact with the scale interior, affecting its microstructure and properties, including its transport behavior. These interactions include the possible dissolution of hydrogen in the oxide and the generation of lattice point defects. Finally, hydrogen generated by a particular reaction can dissolve in the metal itself." @default.
- W32876170 created "2016-06-24" @default.
- W32876170 creator A5003530056 @default.
- W32876170 date "2008-01-01" @default.
- W32876170 modified "2023-10-16" @default.
- W32876170 title "Chapter 10 Effects of Water Vapour on Oxidation" @default.
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- W32876170 doi "https://doi.org/10.1016/s1875-9491(08)00010-0" @default.
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