Matches in SemOpenAlex for { <https://semopenalex.org/work/W329833103> ?p ?o ?g. }
- W329833103 endingPage "232" @default.
- W329833103 startingPage "189" @default.
- W329833103 abstract "In order to study chemical kinetics with any precision it is necessary to have good resolution similar to that accepted for normal analytical studies, and excellent control of temperature. We show how it has been possible to satisfy these two requirements with a high pressure probe constructed for use at the highest magnetic fields. The use of high pressure NMR is then illustrated by a series of specific examples which involve widely differing exchange rates and which embrace a range of rate constants varying over 18 orders of magnitude. The majority of the systems discussed are of solvent exchange on solvated cations, but an example of electron exchange and one of fluxional processes within a protein are also included. The examples illustrate well the unique understanding that knowledge of activation volumes gives to mechanistic processes and the inherent superiority of volume determinations over entropy determinations alone. The specific examples are followed by a more concise overall review of work in the field dealing with solvation complexes of a variety of geometries and with rate processes at pressure in the areas of bioinorganic, organometallic and organic chemistry." @default.
- W329833103 created "2016-06-24" @default.
- W329833103 creator A5004194022 @default.
- W329833103 creator A5026608761 @default.
- W329833103 date "1990-01-01" @default.
- W329833103 modified "2023-10-14" @default.
- W329833103 title "High Resolution Variable Pressure NMR for Chemical Kinetics" @default.
- W329833103 cites W1494689688 @default.
- W329833103 cites W1543159282 @default.
- W329833103 cites W1963747097 @default.
- W329833103 cites W1965436563 @default.
- W329833103 cites W1966267304 @default.
- W329833103 cites W1967929376 @default.
- W329833103 cites W1968106917 @default.
- W329833103 cites W1968192947 @default.
- W329833103 cites W1969843670 @default.
- W329833103 cites W1972244650 @default.
- W329833103 cites W1974892739 @default.
- W329833103 cites W1975591329 @default.
- W329833103 cites W1976773560 @default.
- W329833103 cites W1977449422 @default.
- W329833103 cites W1977485153 @default.
- W329833103 cites W1978485359 @default.
- W329833103 cites W1985362732 @default.
- W329833103 cites W1985690198 @default.
- W329833103 cites W1985853043 @default.
- W329833103 cites W1986497047 @default.
- W329833103 cites W1987140548 @default.
- W329833103 cites W1988610777 @default.
- W329833103 cites W1989973078 @default.
- W329833103 cites W1990367154 @default.
- W329833103 cites W1992845392 @default.
- W329833103 cites W1992871500 @default.
- W329833103 cites W1998888658 @default.
- W329833103 cites W2001121281 @default.
- W329833103 cites W2002073663 @default.
- W329833103 cites W2003300251 @default.
- W329833103 cites W2003775611 @default.
- W329833103 cites W2005388964 @default.
- W329833103 cites W2007002506 @default.
- W329833103 cites W2008032147 @default.
- W329833103 cites W2009033950 @default.
- W329833103 cites W2010943788 @default.
- W329833103 cites W2012996312 @default.
- W329833103 cites W2013615463 @default.
- W329833103 cites W2014191230 @default.
- W329833103 cites W2015534609 @default.
- W329833103 cites W2015665114 @default.
- W329833103 cites W2016616196 @default.
- W329833103 cites W2018144455 @default.
- W329833103 cites W2018795481 @default.
- W329833103 cites W2024120668 @default.
- W329833103 cites W2026156939 @default.
- W329833103 cites W2026667020 @default.
- W329833103 cites W2027538789 @default.
- W329833103 cites W2030997700 @default.
- W329833103 cites W2031620919 @default.
- W329833103 cites W2032097844 @default.
- W329833103 cites W2032619069 @default.
- W329833103 cites W2038998827 @default.
- W329833103 cites W2039968726 @default.
- W329833103 cites W2040509199 @default.
- W329833103 cites W2040944537 @default.
- W329833103 cites W2042791035 @default.
- W329833103 cites W2047117754 @default.
- W329833103 cites W2050795027 @default.
- W329833103 cites W2055594864 @default.
- W329833103 cites W2059789196 @default.
- W329833103 cites W2060858555 @default.
- W329833103 cites W2062085784 @default.
- W329833103 cites W2063253421 @default.
- W329833103 cites W2063295255 @default.
- W329833103 cites W2064198295 @default.
- W329833103 cites W2067164604 @default.
- W329833103 cites W2068109527 @default.
- W329833103 cites W2069309155 @default.
- W329833103 cites W2070235843 @default.
- W329833103 cites W2071127282 @default.
- W329833103 cites W2074097105 @default.
- W329833103 cites W2076587590 @default.
- W329833103 cites W2076709412 @default.
- W329833103 cites W2078744650 @default.
- W329833103 cites W2078839677 @default.
- W329833103 cites W2079489788 @default.
- W329833103 cites W2079609350 @default.
- W329833103 cites W2081119121 @default.
- W329833103 cites W2083586175 @default.
- W329833103 cites W2083626033 @default.
- W329833103 cites W2085457504 @default.
- W329833103 cites W2090401461 @default.
- W329833103 cites W2092585321 @default.
- W329833103 cites W2093602491 @default.
- W329833103 cites W2095417651 @default.
- W329833103 cites W2111618450 @default.
- W329833103 cites W2117405777 @default.
- W329833103 cites W2145196256 @default.
- W329833103 cites W2166910009 @default.
- W329833103 cites W219330778 @default.