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- W330832135 abstract "We have analyzed the factors determining the effect that the composition of aqueous ethanol solvent has on the apparent rate constant k/sub ap/ of acid-catalyzed reactions in which the protonated form of the regent is reactive. An equation is given, which can correlate rate constants of the limiting stages for reactions of this type with different contents of EtOH in the solvent. We have studied the kinetics and proposed a mechanism for the isomerization of 4-hexene-1-yn-3-ol in aqueous and aqueous ethanol solutions of HCl with different compositions at 25/degrees/C. It is shown that the rate constant for monomolecular isomerization of the protonated form of the reagent does not depend on the content of EtOH in the solvent." @default.
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- W330832135 date "1988-11-01" @default.
- W330832135 modified "2023-09-23" @default.
- W330832135 title "Kinetics and mechanism for isomerization of 4-hexene-1-yn-3-ol in aqueous and aqueous ethanol solutions of HCl. Effect of solvent" @default.
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