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- W331364506 abstract "A study of the stabilization of silicone oils at temperatures between 250 and 371 tained C showed that the useful life of the commercially available types may be extended from three to five times by the use of certain oxidation inhibitors known to be effective in other systems. The relative value of different inhibitors varies with the temperature and the aromatic content of the oil. The deterioration of silicones in this temperature range is primarily an oxidative process. This oxidation is inhibited by high-surface solids such as Shawanigan black, copper phthalocyanine, and ferric oxide, by conventional inhibitors of the arylamine type, and by dilauryl selenide. Dilauryl selenide was ineffective at 300 tained C and higher; phenylalphanaphthylamine caused a relatively uniform improvement at 250 and 300 tained C. The gains from any inhibitor were small at 371 tained C. The chemical diversity of the effective inhibitors and the relatively high temperatures at which they are effective suggest that the mechanism of inhibition differs from that operating in conventional oils at temperatures below 200 tained C. The improvements shown with lightly phenylated silicones permit formulation of lubricants having acceptable viscosity characteristics and oxidation stability over the range from -55 tained C ormore » lower to 305 tained C. New types of inhibitors, specifically for use with silicone liquids, which are an order of magnitude more effective than conventional inhibitors were discovered. (auth)« less" @default.
- W331364506 created "2016-06-24" @default.
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- W331364506 date "1960-01-15" @default.
- W331364506 modified "2023-09-26" @default.
- W331364506 title "THE STABILIZATION OF SILICONE LUBRICATING LIQUIDS ABOVE 200 C. PART I. CONVENTIONAL OXIDATION INHIBITORS AND SOME HIGH-SURFACE SOLIDS" @default.
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