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- W331754340 abstract "Spectroscopic rotational temperature measurements on the (0,1) band of the CN violet system gave temperatures which agree with the calculated gas kinetic temperature to about 10%. This method provided a means of inferring a temperature without introducing temperature sensitive devices such as probes in the environment. Rotational intensity measurements on the (0,0) Aln band of the A/sup 1/n--X/sup 1/ SIGMA /sup +/ system revealed an unusual intensity anomaly which is very pressure sensitive. Experiments in the shock tube at high pressure (7 to 13 atmospheres) and in a discharge tube at low pressure (less than one atmosphere) suggested the presence of pressure sensitive strength factors rather than the usual strength factors, or pressure induced predissociation of the excited /sup 1/n state by a postulated /sup 3/ SIGMA state according to the Xronig selection rules. Similar measurements with the Curi (0,0) band (/sup 1/ SIGMA /sup +/ --/sup 1/ SIGMA /sup +/) sh owed that rotational equilibrium is not obtained with this molecule. Time resolved intensity measurements at several pressures indicated that the non-equilibrium condition is due to a forbidden predissociation of the excited /sup 1/ SIGMA /sup +/ state to a /sup 3/ SIGMA / sup +/ state. (auth)" @default.
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- W331754340 date "1959-08-15" @default.
- W331754340 modified "2023-09-24" @default.
- W331754340 title "SHOCK TUBE SPECTROSCOPY. II. SPECTROSCOPIC TEMPERATURE AND INTENSITY MEASUREMENTS IN A SHOCK TUBE. Scientific Report No. 3" @default.
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