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- W332119962 abstract "The imidazolium-2-dithiocarboxylate ligands IPr·CS2, IMes·CS2, and IDip·CS2 react with [AuCl(PPh3)] to yield [(Ph3P)Au(S2C·IPr)]+, [(Ph3P)Au(S2C·IMes)]+, and [(Ph3P)Au(S2C·IDip)]+, respectively. The compounds [(L)Au(S2C·IMes)]+ are prepared from the reaction of IMes·CS2 with [AuCl(L)] (L = PMe3, PCy3, CNtBu). The carbene-containing precursor [(IDip)AuCl] reacts with IPr·CS2 and IMes·CS2 to afford the complexes [(IDip)Au(S2C·IPr)]+ and [(IDip)Au(S2C·IMes)]+ with two carbene units, one bound to the metal center and the other to the dithiocarboxylate unit. Treatment of the diphosphine-gold complex [(dppm)(AuCl)2] with 1 equiv of IMes·CS2 yields [(dppm)Au2(S2C·IMes)]2+, while the reaction of [L2(AuCl)2] (L2 = dppb, dppf) with 2 equiv of IMes·CS2 results in [(L2){Au(S2C·IMes)}2]2+. The homoleptic complexes [Au(S2C·IPr)2]2+, [Au(S2C·IMes)2]2+, and [Au(S2C·IDip)2]2+ are obtained from the reaction of [AuCl(tht)] with 2 equiv of the appropriate imidazolium-2-dithiocarboxylate ligand. The compounds [(Ph3P)Au(S2C·NHC)]+ (NHC = IMes, IDip) and [(IDip)Au(S2C·NHC)]+ (NHC = IPr, IMes) are characterized crystallographically. The IMes·CS2 ligand is also used to prepare functionalized gold nanoparticles with diameters of 11.5 (±1.2) and 2.6 (±0.3) nm." @default.
- W332119962 created "2016-06-24" @default.
- W332119962 creator A5062312496 @default.
- W332119962 creator A5067212029 @default.
- W332119962 creator A5068422233 @default.
- W332119962 creator A5087959120 @default.
- W332119962 date "2010-01-20" @default.
- W332119962 modified "2023-10-12" @default.
- W332119962 title "The Use of Imidazolium-2-dithiocarboxylates in the Formation of Gold(I) Complexes and Gold Nanoparticles†Dedicated to Prof. Dr. Hubert Schmidbaur on the occasion of his 75th birthday." @default.
- W332119962 cites W1532095700 @default.
- W332119962 cites W1821032334 @default.
- W332119962 cites W1895540994 @default.
- W332119962 cites W1965338585 @default.
- W332119962 cites W1965809051 @default.
- W332119962 cites W1968044889 @default.
- W332119962 cites W1969335186 @default.
- W332119962 cites W1970505027 @default.
- W332119962 cites W1971246236 @default.
- W332119962 cites W1971683256 @default.
- W332119962 cites W1972146556 @default.
- W332119962 cites W1981184997 @default.
- W332119962 cites W1982925421 @default.
- W332119962 cites W1985466371 @default.
- W332119962 cites W1988254927 @default.
- W332119962 cites W1988367493 @default.
- W332119962 cites W1988854647 @default.
- W332119962 cites W1991312972 @default.
- W332119962 cites W1998648731 @default.
- W332119962 cites W2000759509 @default.
- W332119962 cites W2002897214 @default.
- W332119962 cites W2003220221 @default.
- W332119962 cites W2006149546 @default.
- W332119962 cites W2006190879 @default.
- W332119962 cites W2009668625 @default.
- W332119962 cites W2010148901 @default.
- W332119962 cites W2010195817 @default.
- W332119962 cites W2014468482 @default.
- W332119962 cites W2018190636 @default.
- W332119962 cites W2019340423 @default.
- W332119962 cites W2023180988 @default.
- W332119962 cites W2032021850 @default.
- W332119962 cites W2033981934 @default.
- W332119962 cites W2035483737 @default.
- W332119962 cites W2035528101 @default.
- W332119962 cites W2036527833 @default.
- W332119962 cites W2036757787 @default.
- W332119962 cites W2043214131 @default.
- W332119962 cites W2045803072 @default.
- W332119962 cites W2046286719 @default.
- W332119962 cites W2046568860 @default.
- W332119962 cites W2049745051 @default.
- W332119962 cites W2053132121 @default.
- W332119962 cites W2055222641 @default.
- W332119962 cites W2057317821 @default.
- W332119962 cites W2059518715 @default.
- W332119962 cites W2060131922 @default.
- W332119962 cites W2062232492 @default.
- W332119962 cites W2062470136 @default.
- W332119962 cites W2072895919 @default.
- W332119962 cites W2075582795 @default.
- W332119962 cites W2077228161 @default.
- W332119962 cites W2078790658 @default.
- W332119962 cites W2083543748 @default.
- W332119962 cites W2084741339 @default.
- W332119962 cites W2085456538 @default.
- W332119962 cites W2086003792 @default.
- W332119962 cites W2086165288 @default.
- W332119962 cites W2086716843 @default.
- W332119962 cites W2088788326 @default.
- W332119962 cites W2090904223 @default.
- W332119962 cites W2092292848 @default.
- W332119962 cites W2092648960 @default.
- W332119962 cites W2095040604 @default.
- W332119962 cites W2095828279 @default.
- W332119962 cites W2100926494 @default.
- W332119962 cites W2104057453 @default.
- W332119962 cites W2113348154 @default.
- W332119962 cites W2114357372 @default.
- W332119962 cites W2133142785 @default.
- W332119962 cites W2139307596 @default.
- W332119962 cites W2143453614 @default.
- W332119962 cites W2169608964 @default.
- W332119962 cites W2321545999 @default.
- W332119962 cites W2334008342 @default.
- W332119962 cites W2334379399 @default.
- W332119962 cites W2492185691 @default.
- W332119962 cites W2952110507 @default.
- W332119962 cites W2953261926 @default.
- W332119962 cites W4244381405 @default.
- W332119962 cites W4248328763 @default.
- W332119962 cites W4252717498 @default.
- W332119962 doi "https://doi.org/10.1021/ic9021504" @default.
- W332119962 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20088565" @default.
- W332119962 hasPublicationYear "2010" @default.
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