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• W332266516 abstract "ABSTRACT The variation of the Cu K-edge x-ray absorption near edge structure (XANES) determined by the structural changes that accompany the loss of oxygen going from the high Tc superconductor YBa2Cu3O7 to the antiferromagnetic insulator YBa2Cu3O6 has been calculated by multiple scattering theory. The elongation of the Cu(2)-O(4) distance (between the Cu(2) in the CuO2 plane and its apical oxygen) induces the shift of the main peak in polarized XANES spectra E//c toward lower energy. The formation of the oxygen vacancies induces changes in the E ⊥ c spectra for the Cu(1) ion in the linear chains. The results are in agreement with the experimental changes of the Cu XANES spectra induced by oxygen vacancies." @default.
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• W332266516 date "1989-01-01" @default.
• W332266516 modified "2023-09-24" @default.
• W332266516 title "ON THE VARIATION OF THE Cu K-EDGE XANES OF YBa2Cu3O7−x WITH OXYGEN CONCENTRATION" @default.
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• W332266516 doi "https://doi.org/10.1016/b978-0-08-037542-7.50029-6" @default.
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