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- W336393985 abstract "The reactivity of small transition-metal particles as a function of their size has been of considerable interest in bridging the gap between homogeneous and heterogeneous catalysis. An obvious approach is to investigate the reactivity of transition-metal clusters or cluster ions as a function of size. Although some reports of such work with neutral clusters have appeared, progress with cluster ions has been hampered by the poor availability of intense sources. Sputtering by kiloelectronvolt atoms or ions promises to be such a source. They now report an extension of their previous investigations of the properties of cluster ions produced by the bombardment of frozen gases to an investigation of the reactions of the gas-phase Ni/sub 1//sup +/-Ni/sub 10//sup +/, Pd/sub 1//sup +/-Pd/sub 4//sup +/, and Pt/sub 1//sup +/, Pt/sub 2//sup +/ ions with n-butane, using the previously described triple-quadrupole secondary-ion mass spectrometer." @default.
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- W336393985 date "1987-02-04" @default.
- W336393985 modified "2023-09-25" @default.
- W336393985 title "Dehydrogenation and cracking of n-butane with gas-phase Ni/sub n//sup +/, Pd/sub n//sup +/, and Pt/sub n//sup +/ cluster ions" @default.
- W336393985 hasPublicationYear "1987" @default.
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