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- W337668736 abstract "Solid state phase transitions are treated as thermodynamic instabilities. Limiting relations between the specific heat cp, thermal expansion coefficients and elastic compliance elements are obtained for certain phases as the transition is approached. For example, such relations hold for alpha -quartz, but not necessarily for beta -quartz. A criterion is given to show whether the behaviour of the high-temperature phase, in regard to such relations, is different to that of the low-temperature form. For alpha -quartz it is shown, using only elastic constant and thermal expansion data, that cp diverges, while for beta -quartz it remains finite, consistent with experiment. The relations derived for the low-temperature forms are similar to the Pippard relations, but have a different constant of proportionality." @default.
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- W337668736 date "1976-03-28" @default.
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- W337668736 title "Thermodynamic relations at solid state phase transitions, applied to the α-β quartz transition" @default.
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- W337668736 doi "https://doi.org/10.1088/0022-3719/9/6/013" @default.
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