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- W338690694 abstract "Thioglycoside-containing trimannose analogs were designed and prepared to mimic the natural N-glycan core trisaccharide α-d-Man-(1→3)-[α-d-Man-(1→6)]-d-Man. (1→6)-S-Linked trimannoside 1 and its trivalent cluster 2 were synthesized in 11 and 15 steps, respectively, taking advantages of the armed mannopyranosyl trichloroacetimidate as glycosyl donor. Hemagglutination inhibition of the two new thiomannotriose analogs was preliminarily examined. Comparing to the parent trimannoside α-d-Man-(1→3)-[α-d-Man-(1→6)]-d-Man-OMe, the cluster mannotrioside 2 presented a comparable binding affinity to Con A, while the monomer 6-S-trimannoside 1 exhibited a slightly lower inhibition ability." @default.
- W338690694 created "2016-06-24" @default.
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- W338690694 date "2015-08-01" @default.
- W338690694 modified "2023-10-17" @default.
- W338690694 title "Synthesis and affinities of C3-symmetric thioglycoside-containing trimannosides" @default.
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- W338690694 doi "https://doi.org/10.1016/j.carres.2015.05.001" @default.
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