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- W339832014 abstract "It was found that a nickel-activated carbon catalyst was effective for vapor phase carbonylation of dimethyl ether and methyl acetate under pressurized conditions in the presence of an iodide promoter. Methyl acetate was formed from dimethyl ether with a yield of 34% and a selectivity of 80% at 250°C and 40 atm, while acetic anhydride was synthesized from methyl acetate with a yield of 12% and a selectivity of 64% at 250°C and 51 atm. In both reactions, high pressure and high CO partial pressure favored the formation of the desired product. In spite of the reaction occurring under water-free conditions, a fairly large amount of acetic acid was formed in the carbonylation of methyl acetate. The route of acetic acid formation is discussed. A molybdenum-activated carbon catalyst was found to catalyze the carbonylation of dimethyl ether and methyl acetate." @default.
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- W339832014 date "1987-12-16" @default.
- W339832014 modified "2023-10-18" @default.
- W339832014 title "Vapor-Phase Carbonylation of Dimethyl Ether and Methyl Acetate with Supported Transition Metal Catalysts" @default.
- W339832014 doi "https://doi.org/10.1021/bk-1987-0328.ch012" @default.
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