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- W339932320 abstract "Thiol-containing aand p-cyclodextrin (CD) derivatives have been synthesized as precursors for the preparation of the analogous monolayers chemisorbed at gold surfaces. The derivatives were formed by the complete replacement of the primary hydroxyl groups at the bottom of the CD cavities of the two oligomers with -S(CH2)2SH groups. The long term goals of this effort is the creation of interfacial structures that exhibit the well known guesthost selectivity of the many solution-soluble forms of CDs. Both solvent and immersion studies of the formation of monolayer have been characterized by infrared reflection spectroscopy, optical ellipsometry, contact angle measurements, x-ray photoelectron spectroscopy, and electrochemistry. The results confirm the formation of monolayers for the adsorbates when DMF was used as the solvent. These results further indicated that both forms of the CD-derivatives adopt an orientation whereby the principle axis of the CD cavity is oriented towards the surface normal. Our findings also reveal that when ethanol or tetrahydrofuran are used as the solvents, multilayer structures are formed that are connected" @default.
- W339932320 created "2016-06-24" @default.
- W339932320 creator A5034540966 @default.
- W339932320 date "2018-08-13" @default.
- W339932320 modified "2023-09-26" @default.
- W339932320 title "The manipulation of interfacial architecture for chemical analysis" @default.
- W339932320 cites W2001835869 @default.
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- W339932320 doi "https://doi.org/10.31274/rtd-180813-13094" @default.
- W339932320 hasPublicationYear "2018" @default.
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