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- W342885229 abstract "Sequential oxidation and reduction of aryl 4, 6-O-benzylidene-β-D-glucosides with dimethyl sulfoxide-phosphorus pentoxide mixture (DMSO-P2O5) and sodium borohydride were carried out as a new means for the preparation of aryl β-D-mannopyranoside derivatives. p-Nitrophenyl 4, 6-O-benzylidene-β-D-mannopyranoside was obtained in 22% yield from the corresponding glucoside 3-O-acetate, whereas from the unprotected acetal, 4, 6-O-benzylidene acetals of the corresponding mannoside and alloside were isolated in the yields of 6.7 and 2.1%, respectively. Similarly, phenyl 4, 6-O-benzylidene β-D-mannoside, alloside, and altroside were obtained from the corresponding glucoside in 2.2, 0.8 and 2.1% yields, respectively." @default.
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- W342885229 date "1976-01-01" @default.
- W342885229 modified "2023-10-04" @default.
- W342885229 title "Oxidation of carbohydrates with dimethyl sulfoxide containing phosphorus pentoxide. III. Preparation of aryl .BETA.-D-mannopyranoside derivatives via .BETA.-D-arabino-hexopyranosiduloses." @default.
- W342885229 doi "https://doi.org/10.1271/bbb1961.40.1621" @default.
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