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• W343589041 abstract "Abstract We have investigated the laser-induced fluorescence (LIF) excitation spectra and dispersed fluorescence (DF) spectra of yttrium monosulfide (YS) in the energy range of 17 860–20 700 cm −1 . Rotational analyses indicated that almost all of the intense vibronic bands can be attributed to the new [ 19.38 ] 2 Σ + ( υ ′ ) - X 2 Σ + ( υ ″ ) transition system. The missing (1, 2), (2, 1) and (3, 3) bands are caused by their very small Franck–Condon factors, as confirmed by our calculations. The new 2 Σ + state has been suggested to arise from the electronic configuration of ( core )1 σ 2 2 σ 2 1 π 3 3 σ 2 π , featuring a charge-transfer nature. Moreover, the spin-rotation parameter γ for the newly observed 2 Σ + state has been determined to be 0.0206 cm −1 , the magnitude of which is larger than the known γ ( X 2 Σ + ) (0.001427 cm −1 ) but smaller than γ ( B 2 Σ + ) (−0.1515 cm −1 )." @default.
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• W343589041 date "2015-07-01" @default.
• W343589041 modified "2023-09-26" @default.
• W343589041 title "The laser-induced fluorescence spectroscopy of yttrium monosulfide" @default.
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• W343589041 doi "https://doi.org/10.1016/j.jms.2015.05.002" @default.
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