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- W34401537 abstract "Results of a microscopic study of sectioned, partially decomposed crystals of silver and potassium permanganates are described. The reaction geometry actually observed has provided a better understanding of the nature of the chain branching processes which have been postulated in order to explain the rapidly accelerating rates of decomposition observed for these crystals. With both substances two-dimensional product chains are formed but the details of the processes differ for the two materials. In the case of AgMnO 4 the branching is localized and usually takes place along certain closely spaced crystallographic planes so that subsequent lateral growth of the plates required for the complete transformation of the crystal is slight. With KMnO 4 , however, the internal decomposition which takes place is neither markedly crystallographic nor localized, and hence subsequent lateral growth is extensive. The internal decomposition is responsible for the mechanical disruption of KMnO 4 ." @default.
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- W34401537 date "1965-01-01" @default.
- W34401537 modified "2023-09-26" @default.
- W34401537 title "MICROSCOPIC INVESTIGATION OF THE THERMAL DECOMPOSITION OF SILVER AND POTASSIUM PERMANGANATES" @default.
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- W34401537 doi "https://doi.org/10.1016/b978-1-4831-9831-6.50012-6" @default.
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