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- W34531418 abstract "The kinetics and mechanism of processes of cumene hydroperoxide catalytic decomposition and cyclohexane oxidation by cumene hydroperoxide in benzene solutions of cobaltous complexes of tetra-4-tert-butylphthalocyanine (tPcCo) and tetra-tert-butyltetrazaporphine at 20°C were studied in detail. Both processes were shown to be catalyzed in case of tPcCo not only by complex itself but also by the product of its reversible oxidation on macrocycle. The oxidation of central metal atom results in formation of catalytically inactive forms. The occurence and ratio of molecular and radical hydroperoxide decomposition routes were established. The products of the latter one are oxidizing cyclohexane when introducing it in the system. The mechanism of cyclohexane oxidation and novel efficient catalysts for this process were proposed." @default.
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- W34531418 date "1991-01-01" @default.
- W34531418 modified "2023-10-16" @default.
- W34531418 title "Hydroperoxide Oxidation of Cyclohexane Catalyzed by Metal Complexes of Azaporphines" @default.
- W34531418 cites W2054162205 @default.
- W34531418 doi "https://doi.org/10.1016/s0167-2991(08)62866-9" @default.
- W34531418 hasPublicationYear "1991" @default.
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