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- W346774163 abstract "An extensive search of the literature has been made for ion exchange data on smectites, certain zeolites and basalt. The data are in the form of thermodynamic equilibrium constants, corrected selectivity coefficients, and distribution coefficients. Room temperature alkali and alkaline earth metal cation ion exchange data for smectites are extensive. Correlation between the exchange free energies of alkali metal cations on Camp Berteau montmorillonite values with their Debeye-Hueckel parameter was found. Significant differences in values of exchange constants for the same reaction on different smectites were noted. While this in part may be attributable to differences in experimental procedures, much of the variance is probably due to differences in charge densities and the effective field strengths of the smectites. Differences in field strength are related to the type and amount of substitution on intercrystalline octahedral and tetrahedral sites. Data on smectites suggest that cation exchange selectivities are very strong functions of temperature. Experiments on the exchange properties of clinoptilolite and mordenite have been generally confined to alkali and alkaline earth cations although data for certain transition metal ions are also available for synthetic mordenite. The temperature dependences of zeolite exchange selectivities remain largely unknown. Distribution coefficients for groundwater-basalt systems have been measured for a variety of elements at temperatures up to 150/sup 0/C. Steady state concentrations are often never achieved either from the sorption or the desorption side. Classical models of ion exchange have been applied successfully to zeolite and smectite exchange reactions. The sorption behavior of a basalt is better treated with models of the interface which take surface ionization and complexation into account." @default.
- W346774163 created "2016-06-24" @default.
- W346774163 creator A5081911407 @default.
- W346774163 date "1980-05-01" @default.
- W346774163 modified "2023-09-27" @default.
- W346774163 title "Tabulation and evaluation of ion exchange data on smectites, certain zeolites and basalt" @default.
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- W346774163 doi "https://doi.org/10.2172/5168609" @default.
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