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- W3506297 abstract "The specific resistance and magnetic susceptibility measured for LaI2 clearly support the metallic formulation La3+ (I-)2e-. A comparable temperature dependence of resistivity was obtained for a mixed phase sample of CeI2. The formation of apparently metallic phases for only the iodides of five lanthanide and actinide elements is considered in terms of the stoichiometry, the electronic structure of the cation, the possible nature of the band, and the role of the anion. In contrast, the intermediate LaI2.42 phase exhibits semiconduction. Its magnetic data between 80° and 300°K. can be best accounted for if the reduced component is considered to be La2+, [Xe]5d1, with a 2T2g ground term, a spin-orbit coupling constant λ ∼650 cm.-1, and only small covalency and asymmetry parameters." @default.
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- W3506297 date "1967-06-01" @default.
- W3506297 modified "2023-10-16" @default.
- W3506297 title "Physical Characterization of the Metallic LaI<sub>2</sub> and CeI<sub>2</sub> and of the Phase LaI<sub>2.42</sub>" @default.
- W3506297 doi "https://doi.org/10.1021/ba-1967-0071.ch005" @default.
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