Matches in SemOpenAlex for { <https://semopenalex.org/work/W359980552> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W359980552 abstract "Part 1 Introduction: history of aromatic and heteroaromatic diazo compounds nomenclature general references. Part 2 Methods for the preparation of aromatic and heteroaromatic diazo compounds: diazotization of amines with alkali nitrite in dilute aqueous mineral acids diazotization in concentrated mineral acid isolation of diazonium salts diazotization of 2- and 4-aminophenols formation of diazonium salts under anhydrous conditions other reactions involving formation of aromatic diazonium ions. Part 3 Kinetics and mechanism of diazotization: historical development influence of acidity on the rate and mechanism of diazotization in aqueous sulfuric and perchloric acids nucleophilic catalysis of diazotization transformation of the N-Nitrosoamine intermediate into the diazonium ion. Part 4 The structure of diazonium compounds: introductory remarks structure of arenediazonium salts theoretical investigations. Part 5 Acid-base and isomerization reactions of diazo compounds in water: the aromatic diazonium ion as a dibasic acid the combined system of acid-base addition, (Z)/(E)- and prototropic isomerization reactions of arenediazonium ions kinetics and equilibria of arenediazonium ions in water. Part 6 Additions of other nucleophiles to arenediazonium ions: O-Coupling S-coupling N-coupling P-coupling C-coupling intramolecular coupling. Part 7 Structural and mechanistic aspects of additions of nucleophiles to diazonium ions: (Z)/(E)-isomerism investigations on reactivities by the interpretation of substituent effects - the Hammett and related equations the electronic influence of the diazonio group as a substituent influence of substituents on the addition of nucleophiles to arenediazonium ions. Part 8 Dediazoniation of arenediazonium ions: introduction to dediazoniation in general multiplicity of pathways and products the D[N] + A[N] mechanism of dediazoniation molecular orbital investigations on heterolytic dediazoniations and on aryl cations dediazoniations via aryne intermediates dediazoniation initiated by an electron transfer solvent effects in competitive homolytic and heterolytic dediazoniation dediazoniation in alkaline aqueous solutions dediazoniation in highly nucleophilic solvents and in the presence of good nucleophiles dediazoniation in alcohols. Part 9 Logic, psychology, and serendipity of scientific discoveries - an interlude. Part 10 Applications of heterolytic and homolytic dediazoniations in organic syntheses: hydro-de-diazoniation hydroxy- and mercapto-de-diazoniations and related reactions fluoro-de-diazoniation chloro-, bromo-, and cyano-de-diazoniations - the Sandmeyer reaction iodo-de-diazoniation and related reactions azido-de-diazoniation dediazoniation in the presence of carbonyl, sulfonyl, and related compounds replacement of the diazonio group by alkenes and alkynes - the Meerwein reaction arylation of aromatic compounds - the Gomberg-Bachmann and related reactions. (Part contents)." @default.
- W359980552 created "2016-06-24" @default.
- W359980552 creator A5042970297 @default.
- W359980552 date "1994-01-01" @default.
- W359980552 modified "2023-09-25" @default.
- W359980552 title "Aromatic and Heteroaromatic Compounds" @default.
- W359980552 hasPublicationYear "1994" @default.
- W359980552 type Work @default.
- W359980552 sameAs 359980552 @default.
- W359980552 citedByCount "2" @default.
- W359980552 crossrefType "journal-article" @default.
- W359980552 hasAuthorship W359980552A5042970297 @default.
- W359980552 hasConcept C126661725 @default.
- W359980552 hasConcept C145148216 @default.
- W359980552 hasConcept C161790260 @default.
- W359980552 hasConcept C178790620 @default.
- W359980552 hasConcept C178907741 @default.
- W359980552 hasConcept C184651966 @default.
- W359980552 hasConcept C185592680 @default.
- W359980552 hasConcept C2776904781 @default.
- W359980552 hasConcept C2777250486 @default.
- W359980552 hasConcept C2778199549 @default.
- W359980552 hasConcept C2778689049 @default.
- W359980552 hasConcept C2909835963 @default.
- W359980552 hasConcept C30095370 @default.
- W359980552 hasConceptScore W359980552C126661725 @default.
- W359980552 hasConceptScore W359980552C145148216 @default.
- W359980552 hasConceptScore W359980552C161790260 @default.
- W359980552 hasConceptScore W359980552C178790620 @default.
- W359980552 hasConceptScore W359980552C178907741 @default.
- W359980552 hasConceptScore W359980552C184651966 @default.
- W359980552 hasConceptScore W359980552C185592680 @default.
- W359980552 hasConceptScore W359980552C2776904781 @default.
- W359980552 hasConceptScore W359980552C2777250486 @default.
- W359980552 hasConceptScore W359980552C2778199549 @default.
- W359980552 hasConceptScore W359980552C2778689049 @default.
- W359980552 hasConceptScore W359980552C2909835963 @default.
- W359980552 hasConceptScore W359980552C30095370 @default.
- W359980552 hasLocation W3599805521 @default.
- W359980552 hasOpenAccess W359980552 @default.
- W359980552 hasPrimaryLocation W3599805521 @default.
- W359980552 hasRelatedWork W1540605278 @default.
- W359980552 hasRelatedWork W1552200509 @default.
- W359980552 hasRelatedWork W1568477163 @default.
- W359980552 hasRelatedWork W170487507 @default.
- W359980552 hasRelatedWork W1921750874 @default.
- W359980552 hasRelatedWork W1994949134 @default.
- W359980552 hasRelatedWork W2042005478 @default.
- W359980552 hasRelatedWork W2075029904 @default.
- W359980552 hasRelatedWork W2099288267 @default.
- W359980552 hasRelatedWork W2107789026 @default.
- W359980552 hasRelatedWork W2134419526 @default.
- W359980552 hasRelatedWork W2333756027 @default.
- W359980552 hasRelatedWork W2506395849 @default.
- W359980552 hasRelatedWork W2897851016 @default.
- W359980552 hasRelatedWork W2949365955 @default.
- W359980552 hasRelatedWork W2949604529 @default.
- W359980552 hasRelatedWork W2952869226 @default.
- W359980552 hasRelatedWork W2952942599 @default.
- W359980552 hasRelatedWork W2953244708 @default.
- W359980552 hasRelatedWork W586591777 @default.
- W359980552 isParatext "false" @default.
- W359980552 isRetracted "false" @default.
- W359980552 magId "359980552" @default.
- W359980552 workType "article" @default.