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- W36197971 abstract "Abstract A twin calorimeter has been developed which makes it possible to measure the total heat effect of an electrochemical reaction and, at the same time and separately, the heat effect associated with the cathodic reaction and the anodic reaction. Each electrode is contained in a vacuum jacketed compartment; the two compartments are separated by a filter paper partition. To avoid thermoelectric effects the two compartments are maintained at the same temperature during the electrolysis. The calorimeter was tested by measuring the heat effects during the electrolysis of a dilute sulfuric acid solution. Excellent agreement with the accepted value for the heat of formation of water was obtained. The technique was extended to include systems of copper sulfate-copper and silver nitrate-silver. The enthalpy change for the total reaction as well as the entropy change for the reaction occurring at each electrode was determined." @default.
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- W36197971 date "1965-01-01" @default.
- W36197971 modified "2023-09-28" @default.
- W36197971 title "HEAT EFFECTS AT ELECTRODES" @default.
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- W36197971 doi "https://doi.org/10.1016/b978-1-4831-9831-6.50018-7" @default.
- W36197971 hasPublicationYear "1965" @default.
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