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- W36610147 abstract "Given the multiple synthesis methods, polyolefins (PO) are found within a wide property range that is determined primarily by their basic chemical structure. The study of their chemical features can be difficult due to the many possibilities of structural arrangements and increasing complexity that requires the conjunction of many instrumental techniques. This chapter defines the structure of PO, polyethylene (PE), and polypropylene (PP) of highest commercial importance, through a comparative study of the infrared spectra, in order to find all the information, which is possibly available by this technique. Besides infrared spectroscopy, differential scanning calorimeter results (DSC) are frequently used for determining certain important thermal properties directly associated with morphology and crystallinity. PEs of different densities can be distinguished by certain characteristic features in the structure, which are perfectly seen in the IR spectra and in the DSC curves. These differences are mainly short branching as hexyl and ethyl, unsaturations of the internal trans-vinylene, vinyl, vinylidene, and allyl type." @default.
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- W36610147 date "1999-01-01" @default.
- W36610147 modified "2023-09-27" @default.
- W36610147 title "New Polyolefins Characterization by Instrumental Analysis" @default.
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- W36610147 doi "https://doi.org/10.1016/b978-188420776-1.50025-9" @default.
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