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- W36956081 abstract "Preparation of zirconium polycation-exchanged montmorillonite, which was promoted by sulfate ion, was examined in terms of the ion exchanging process and sulfation process. The acidic properties and the catalytic activities of thus prepared catalyst was examined by the isomerizations of 1-butene and cyclopropane and the disproportionation of alkylsilanes as well as the FT-IR of adsorbed basic molecules. It was found that the aging of the exchanging solution (ZrOCI 2 solution) by reflux has a fatal importance to obtain a high surface area with a large interlayer-spacing pillared clays. A sulfation of thus obtained pillared clays gave a remarkable enhancement in acidic properties." @default.
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- W36956081 date "1994-01-01" @default.
- W36956081 modified "2023-10-16" @default.
- W36956081 title "3.3 Synthesis and Catalytic Properties of Sulfate Ion-Promoted Zr-Pillared Clays" @default.
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- W36956081 doi "https://doi.org/10.1016/s0167-2991(08)61829-7" @default.
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