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- W376087839 abstract "Analysis of all available data of published pure rotational and vibration-rotational spectra of Al35 Cl, Al37 Cl, and SiS in various isotopic variants yielded values of coefficients of radial functions for the potential energy and other molecular properties for the electronic ground statesX 1Σ+; only ten independently fitted parameters sufficed to reproduce satisfactorily and with physical meaning the frequencies and wavenumbers of about 890 distinct pure rotational and vibration-rotational transitions of AlCl, but ten parameters were fitted to 3025 transitions of SiS with two constrained parameters. Effectively independent of nuclear mass, the equilibrium internuclear separation of AlClR e/10−10m=2.1301429±0.0000019, and the maximum range of validity of the radial functions is 1.90≤R/10−10m≤2.48, whereas for SiSR e/10−10m=1.9292731±0.0000016 and the maximum range of radial functions is 1.72≤R/10−10m≤2.25. Comparisons with previously published results of both AlCl and SiS are made." @default.
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- W376087839 date "1994-09-01" @default.
- W376087839 modified "2023-10-16" @default.
- W376087839 title "The inversion of spectral data of AlCl and SiSX 1Σ+" @default.
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- W376087839 doi "https://doi.org/10.1007/bf03156408" @default.
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