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- W379163134 abstract "The addition of acrylaldehyde (2) and allylalcohol (3) to alloocimene (1) (mixture of (4E, 6E)-(1 a) and (4E, 6Z)-alloocimene (1 b)) was investigated.In the case of addition of (2) to (A, the four possible acrylaldehyde adduts were isolated and their structures(t-2-(2-methyl-1-prQpeny1)-4, 5-dimethy1-3-cyclohexene- 1-carboxaldehyde (4), t-2-(2-methyl-1-propenyl)-4, c-5-dimethyl-3-cyclohexqne-r-1-carboxaldehyde (5), c-2-(2-methyl1-propenyi)-4, t-5-dimethyl-3-cyclohexene-r-1-carboxaldehyde (6), c-2-(2-methyl-1-propenyl)-4, c-5-dimethy1-3-cyclohexene -1-carboxaldehyde(7))were established chieflyon the basis of COmparisons of their reduction products with the authentic samples of tww2w(2-methyl-1-propenyl)4)t-5-dimethyl-3-cyclohexene-r-1-methanol(8), t-2-(2-methyl-1-propenyl)-4, c-5-dimethyl-3cyc1ohexene-r-1-methano 99, -2-(2-methy1-1-propenyl)-4, t-5-dimethy1-3-cyclohexene- -1- ethanol(10)and -2-(2-methy1-1-propenyl)-4, c-5-dimethy1-3-cyclohexene-1-methanol(11)OR the other hand, in the case of addition of (3) to (1), their structures ((8), v(11)) were established by means of a same methode as before. (4)N(7) and (8). Nt(11) have a mild wood-like odor." @default.
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- W379163134 date "1973-01-01" @default.
- W379163134 modified "2023-09-23" @default.
- W379163134 title "Diels-Alder Reaction of (4E, 6E)- and (4E, 6Z)-Alloocimene with Acrylaldehyde and AIIylalcohol" @default.
- W379163134 doi "https://doi.org/10.1246/nikkashi.1973.1064" @default.
- W379163134 hasPublicationYear "1973" @default.
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